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This reaction gives the methanol solvate of the dichloride, which upon heating in a vacuum at about 160 °C converts to anhydrous FeCl 2. [4] The net reaction is shown: Fe + 2 HCl → FeCl 2 + H 2. FeBr 2 and FeI 2 can be prepared analogously. An alternative synthesis of anhydrous ferrous chloride is the reduction of FeCl 3 with chlorobenzene: [5]
The ammonia from reaction (III) is recycled back to the initial brine solution of reaction (I). The sodium bicarbonate (NaHCO 3) precipitate from reaction (I) is then converted to the final product, sodium carbonate (washing soda: Na 2 CO 3), by calcination (160–230 °C), producing water and carbon dioxide as byproducts:
Sodium bicarbonate (IUPAC name: sodium hydrogencarbonate [9]), commonly known as baking soda or bicarbonate of soda, is a chemical compound with the formula NaHCO 3. It is a salt composed of a sodium cation (Na +) and a bicarbonate anion (HCO 3 −). Sodium bicarbonate is a white solid that is crystalline but often appears as a
For many substances, the formation reaction may be considered as the sum of a number of simpler reactions, either real or fictitious. The enthalpy of reaction can then be analyzed by applying Hess' law, which states that the sum of the enthalpy changes for a number of individual reaction steps equals the enthalpy change of the overall reaction.
Ammonium chloride reacts with a strong base, like sodium hydroxide, to release ammonia gas: NH 4 Cl + NaOH → NH 3 + NaCl + H 2 O. Similarly, ammonium chloride also reacts with alkali-metal carbonates at elevated temperatures, giving ammonia and alkali-metal chloride: 2 NH 4 Cl + Na 2 CO 3 → 2 NaCl + CO 2 + H 2 O + 2 NH 3
Iron(II) chloride tetrahydrate, FeCl 2 ·4H 2 O. In chemistry, iron(II) refers to the element iron in its +2 oxidation state.The adjective ferrous or the prefix ferro-is often used to specify such compounds, as in ferrous chloride for iron(II) chloride (FeCl 2).
Related is the reaction of mercury(II) chloride with ammonia (Calomel reaction), where the resulting mercuric amidochloride is highly insoluble. HgCl 2 + 2 NH 3 → HgCl(NH 2) + [NH 4]Cl. The ammine ligands are more acidic than is ammonia (pK a ~ 33). For highly cationic complexes such as [Pt(NH 3) 6] 4+, the conjugate base can be obtained.
A chemical reaction is a process that leads to the chemical transformation of one set of chemical substances to another. [1] When chemical reactions occur, the atoms are rearranged and the reaction is accompanied by an energy change as new products are generated.