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According to the rules of IUPAC nomenclature, ketone names are derived by changing the suffix-ane of the parent alkane to -anone. Typically, the position of the carbonyl group is denoted by a number, but traditional nonsystematic names are still generally used for the most important ketones, for example acetone and benzophenone.
Pages in category "Ketones" The following 200 pages are in this category, out of approximately 482 total. This list may not reflect recent changes.
Pages in category "Ketone solvents" The following 14 pages are in this category, out of 14 total. This list may not reflect recent changes. A. Acetone; Acetophenone; B.
For example, methanol has been shown to promote aryl migration. [11] [12] As shown below, if the reaction of piperanol (IV) with diazomethane is carried out in the absence of methanol, the ketone obtained though a hydride shift is the major product (V). If methanol is the solvent, an aryl shift occurs to form the aldehyde (VI), which cannot be ...
Common names for ketones can be derived by naming the two alkyl or aryl groups bonded to the carbonyl group as separate words followed by the word ketone. Acetone; Acetophenone; Benzophenone; Ethyl isopropyl ketone; Diethyl ketone; The first three of the names shown above are still considered to be acceptable IUPAC names.
Geminal diols can be viewed as ketone (or aldehyde) hydrates. The two hydroxyl groups in a geminal diol are easily converted to a carbonyl or keto group C=O by loss of one water molecule. Conversely, a keto group can combine with water to form the geminal hydroxyl groups. The equilibrium in water solution may be shifted towards either compound.
In monometallic complexes, aldehydes and ketones can bind to metals in either of two modes, η 1-O-bonded and η 2-C,O-bonded. These bonding modes are sometimes referred to sigma- and pi-bonded. These forms may sometimes interconvert. The sigma bonding mode is more common for higher valence, Lewis-acidic metal centers (e.g., Zn 2+). [1]
A classic example for favoring the keto form can be seen in the equilibrium between vinyl alcohol and acetaldehyde (K = [enol]/[keto] ≈ 3 × 10 −7). In 1,3-diketones, such as acetylacetone (2,4-pentanedione), the enol form is more favored. The acid-catalyzed conversion of an enol to the keto form proceeds by proton transfer from O to carbon.