Search results
Results From The WOW.Com Content Network
Molar enthalpy of zinc above 298.15 K and at 1 atm pressure, showing discontinuities at the melting and boiling points. The enthalpy of melting (ΔH°m) of zinc is 7323 J/mol, and the enthalpy of vaporization (ΔH°v) is 115 330 J/mol. The enthalpy of vaporization can be written as
The third column is the heat content of each gram of the liquid phase relative to water at 0 °C. The fourth column is the heat of vaporization of each gram of liquid that changes to vapor. The fifth column is the work PΔV done by each gram of liquid that changes to vapor. The sixth column is the density of the vapor.
Water has a very high specific heat capacity of 4184 J/(kg·K) at 20 °C (4182 J/(kg·K) at 25 °C) —the second-highest among all the heteroatomic species (after ammonia), as well as a high heat of vaporization (40.65 kJ/mol or 2268 kJ/kg at the normal boiling point), both of which are a result of the extensive hydrogen bonding between its ...
J.A. Dean (ed.), Lange's Handbook of Chemistry (15th Edition), McGraw-Hill, 1999; Section 6, Thermodynamic Properties; Table 6.4, Heats of Fusion, Vaporization, and Sublimation and Specific Heat at Various Temperatures of the Elements and Inorganic Compounds
Note that the especially high molar values, as for paraffin, gasoline, water and ammonia, result from calculating specific heats in terms of moles of molecules. If specific heat is expressed per mole of atoms for these substances, none of the constant-volume values exceed, to any large extent, the theoretical Dulong–Petit limit of 25 J⋅mol ...
Finally Black increased the temperature of and vaporized respectively two equal masses of water through even heating. He showed that 830 “degrees of heat” was needed for the vaporization; again based on the time required. The modern value for the heat of vaporization of water would be 967 “degrees of heat” on the same scale. [19]
A closely related property of a substance is the heat capacity per mole of atoms, or atom-molar heat capacity, in which the heat capacity of the sample is divided by the number of moles of atoms instead of moles of molecules. So, for example, the atom-molar heat capacity of water is 1/3 of its molar heat capacity, namely 25.3 J⋅K −1 ⋅mol ...
For a liquid–gas transition, is the molar latent heat (or molar enthalpy) of vaporization; for a solid–gas transition, is the molar latent heat of sublimation. If the latent heat is known, then knowledge of one point on the coexistence curve , for instance (1 bar, 373 K) for water, determines the rest of the curve.