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The −SH functional group itself is referred to as either a thiol group or a sulfhydryl group, or a sulfanyl group. Thiols are the sulfur analogue of alcohols (that is, sulfur takes the place of oxygen in the hydroxyl ( −OH ) group of an alcohol), and the word is a blend of " thio- " with "alcohol".
In organic chemistry, a dithiol is a type of organosulfur compound with two thiol (−SH) functional groups. Their properties are generally similar to those of monothiols in terms of solubility, odor, and volatility. They can be classified according to the relative location of the two thiol groups on the organic backbone. Structure of some dithiols
The reactivity of a functional group can be modified by other functional groups nearby. Functional group interconversion can be used in retrosynthetic analysis to plan organic synthesis. A functional group is a group of atoms in a molecule with distinctive chemical properties, regardless of the other atoms in the molecule. The atoms in a ...
Polyphenylene sulfide (see below) has the empirical formula C 6 H 4 S. Occasionally, the term sulfide refers to molecules containing the –SH functional group. For example, methyl sulfide can mean CH 3 –SH. The preferred descriptor for such SH-containing compounds is thiol or mercaptan, i.e. methanethiol, or methyl mercaptan.
Thiophenol is an organosulfur compound with the formula C 6 H 5 SH, sometimes abbreviated as PhSH. This foul-smelling colorless liquid is the simplest aromatic thiol.The chemical structures of thiophenol and its derivatives are analogous to phenols, where the oxygen atom in the hydroxyl group (-OH) bonded to the aromatic ring in phenol is replaced by a sulfur atom.
The functional groups on the thiol and alkene compounds can affect the reactivity of the radical species and their respective rate constants. The structure of the alkene determines whether the reaction will be propagation or chain-transfer limited, and therefore first order with respect to alkene or thiol concentration respectively.
Thiol groups contain the functionality R−SH. Thiols are structurally similar to the alcohol group, but these functionalities are very different in their chemical properties. Thiols are more nucleophilic, more acidic, and more readily oxidized.
The side chains are grouped like this: 12-butyl-4,8-diethyl. (But this is not necessarily the final grouping, as functional groups may be added in between to ensure all groups are listed alphabetically.) The secondary functional groups are: a hydroxy- at carbon 5, a chloro- at carbon 11, a methoxy- at carbon 15, and a bromo- at carbon 18.