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The combination of urea and ammonium nitrate has an extremely low critical relative humidity (18% at 30 °C) and can therefore only be used in liquid fertilizers. The most commonly used grade of these fertilizer solutions is UAN 32.0.0 (32%N) known as UN32 or UN-32, which consists of 45% ammonium nitrate , 35% urea and only 20% water.
Urea nitrate is a fertilizer-based high explosive that has been used in improvised explosive devices in Afghanistan, Pakistan, Iraq, and various terrorist acts elsewhere in the world such as in the 1993 World Trade Center bombings. [2]
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UAN is a solution of urea and ammonium nitrate in water used as a fertilizer. Uan or UAN may also refer to: Adapa, an alternate name for the first of the Mesopotamian seven sages; Autonomous University of Nayarit (in Spanish: Universidad Autónoma de Nayarit), a Mexican public university based in the city of Tepic, Nayarit
The structure of the molecule of urea is O=C(−NH 2) 2.The urea molecule is planar when in a solid crystal because of sp 2 hybridization of the N orbitals. [8] [9] It is non-planar with C 2 symmetry when in the gas phase [10] or in aqueous solution, [9] with C–N–H and H–N–H bond angles that are intermediate between the trigonal planar angle of 120° and the tetrahedral angle of 109.5°.
These can be called urea adducts or if a solvent is involved, a urea solvate, and the process is called urea extraction crystallization. Urea can also be a neutral ligand if it is coordinated to a central metal atom. Urea can form hydrogen bonds to other oxygen and nitrogen atoms in the substance it crystallises with.
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The soil's pH also has a strong effect on the amount of volatilization. Specifically, highly alkaline soils (pH~8.2 or higher) have proven to increase urea hydrolysis. One study has shown complete hydrolysis of urea within two days of application on such soils. In acidic soils (pH 5.2) the urea took twice as long to hydrolyze. [7]