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Typical crack pattern of the alkali-silica reaction (ASR). The gel exudations through the concrete cracks have a characteristic yellow color and a high pH. The fatty aspect of the exudations imbibing the concrete porosity along the cracks is also a distinctive feature of ASR. The alkali-silica reaction as a chemical cycle process
4 ions can also be trapped, or sorbed, into the layered structure of C-S-H. [3] These successive reactions lead to the precipitation of expansive mineral phases inside the concrete porosity responsible for the concrete degradation, cracks and ultimately the failure of the structure.
The curing of concrete when it continues to harden after its initial setting and progressively develops its mechanical strength is a critical phase to avoid unwanted cracks in concrete. Depending on the temperature (summer or winter conditions) and thus on the cement hydration kinetics controlling the setting and hardening rate of concrete ...
This reaction is expansive, and can disrupt mature concrete. Where concrete is to be placed in contact with, for example, sulfate-laden ground waters, either a "sulfate-resisting" cement (with low levels of tricalcium aluminate) is used, or slag is added to the cement or to the concrete mix. The slag contributes sufficient aluminium to suppress ...
Aluminium sulfate may be used as a deodorant, an astringent, or as a styptic for superficial shaving wounds. [citation needed] Aluminium sulfate is used as a mordant in dyeing and printing textiles. It is a common vaccine adjuvant and works "by facilitating the slow release of antigen from the vaccine depot formed at the site of inoculation."
For ordinary Portland cement, it reacts with the calcium hydroxide in concrete to form calcium sulfate. This change simultaneously destroys the polymeric nature of calcium hydroxide and substitutes a larger molecule into the matrix causing pressure and spalling of the adjacent concrete and aggregate particles. [ 7 ]
The cement is a hydraulic binder whose hydration requires water. It can perfectly set under water. Water is essential to its hardening and water losses must be avoided at the young age to avoid the development of cracks. Young concrete is protected against desiccation (evaporation of unreacted water). Traditional methods for preventing ...
The term ‘acid sulfate soils’ (ASS) was coined by the Working Party on Nomenclature and Methods for the first International Symposium on Acid Sulfate Soils (1972, Wageningen) to mean soils that contain, or have the potential to produce, sulfuric acid in quantities that cause significant and long-lasting changes in key soil properties. [22]