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The electric dipole moment is a measure of the separation of positive and negative electrical charges within a system: that is, a measure of the system's overall polarity. The SI unit for electric dipole moment is the coulomb - meter (C⋅m). The debye (D) is another unit of measurement used in atomic physics and chemistry.
The transition dipole moment or transition moment, usually denoted for a transition between an initial state, , and a final state, , is the electric dipole moment associated with the transition between the two states. In general the transition dipole moment is a complex vector quantity that includes the phase factors associated with the two states.
Dipolar compound. In organic chemistry, a dipolar compound or simply dipole is an electrically neutral molecule carrying a positive and a negative charge in at least one canonical description. In most dipolar compounds the charges are delocalized. [1] Unlike salts, dipolar compounds have charges on separate atoms, not on positive and negative ...
An example in organic chemistry of the role of geometry in determining dipole moment is the cis and trans isomers of 1,2-dichloroethene. In the cis isomer the two polar C−Cl bonds are on the same side of the C=C double bond and the molecular dipole moment is 1.90 D. In the trans isomer, the dipole moment is zero because the two C−Cl bonds are on opposite sides of the C=C and cancel (and ...
In chemistry, polarity is a separation of electric charge leading to a molecule or its chemical groups having an electric dipole moment, with a negatively charged end and a positively charged end. Polar molecules must contain one or more polar bonds due to a difference in electronegativity between the bonded atoms.
Polarizability. Polarizability usually refers to the tendency of matter, when subjected to an electric field, to acquire an electric dipole moment in proportion to that applied field. It is a property of particles with an electric charge. When subject to an electric field, the negatively charged electrons and positively charged atomic nuclei ...
A dipole is characterised by its dipole moment, a vector quantity shown in the figure as the blue arrow labeled M. It is the relationship between the electric field and the dipole moment that gives rise to the behaviour of the dielectric. (Note that the dipole moment points in the same direction as the electric field in the figure.
Topological dipole moment, the measure of the topological defect charge distribution. The first order term (or the second term) of the multipole expansion of a function. The dielectric constant of a solvent; the measure of its capacity to break the covalent molecules into ions.