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The definition of strain rate was first introduced in 1867 by American metallurgist Jade LeCocq, who defined it as "the rate at which strain occurs. It is the time rate of change of strain." In physics the strain rate is generally defined as the derivative of the strain with respect to time. Its precise definition depends on how strain is measured.
A two-dimensional flow that, at the highlighted point, has only a strain rate component, with no mean velocity or rotational component. In continuum mechanics, the strain-rate tensor or rate-of-strain tensor is a physical quantity that describes the rate of change of the strain (i.e., the relative deformation) of a material in the neighborhood of a certain point, at a certain moment of time.
The strain energy of cyclopropane and cyclobutane are 27.5 and 26.3 kcal mol −1, respectively. [1] Cyclopentane experiences much less strain, mainly due to torsional strain from eclipsed hydrogens: its preferred conformations interconvert by a process called pseudorotation. [4]: 14 Ring strain can be considerably higher in bicyclic systems.
In mechanics, strain is defined as relative deformation, compared to a reference position configuration. Different equivalent choices may be made for the expression of a strain field depending on whether it is defined with respect to the initial or the final configuration of the body and on whether the metric tensor or its dual is considered.
Castigliano's method for calculating displacements is an application of his second theorem, which states: If the strain energy of a linearly elastic structure can be expressed as a function of generalised force Q i then the partial derivative of the strain energy with respect to generalised force gives the generalised displacement q i in the direction of Q i.
where k s is the rate of the studied reaction and is the rate of the reference reaction (R = methyl). δ is a reaction constant that describes the susceptibility of a reaction series to steric effects. For the definition reaction series δ was set to 1 and E s for the reference reaction was set to zero. This equation is combined with the ...
In chemistry, the rate equation (also known as the rate law or empirical differential rate equation) is an empirical differential mathematical expression for the reaction rate of a given reaction in terms of concentrations of chemical species and constant parameters (normally rate coefficients and partial orders of reaction) only. [1]
Using the Eyring equation, there is a straightforward relationship between ΔG ‡, first-order rate constants, and reaction half-life at a given temperature. At 298 K, a reaction with ΔG ‡ = 23 kcal/mol has a rate constant of k ≈ 8.4 × 10 −5 s −1 and a half life of t 1/2 ≈ 2.3 hours, figures that are often rounded to k ~ 10 −4 s ...