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This constitutive equation is also called the Newton law of viscosity. The total stress tensor σ {\displaystyle {\boldsymbol {\sigma }}} can always be decomposed as the sum of the isotropic stress tensor and the deviatoric stress tensor ( σ ′ {\displaystyle {\boldsymbol {\sigma }}'} ):
Newton's law of viscosity is not a fundamental law of nature, but rather a constitutive equation (like Hooke's law, Fick's law, and Ohm's law) which serves to define the viscosity . Its form is motivated by experiments which show that for a wide range of fluids, μ {\displaystyle \mu } is independent of strain rate.
Isaac Newton showed that for many familiar fluids such as water and air, the stress due to these viscous forces is linearly related to the strain rate. Such fluids are called Newtonian fluids. The coefficient of proportionality is called the fluid's viscosity; for Newtonian fluids, it is a fluid property that is independent of the strain rate.
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In physics and chemistry, a non-Newtonian fluid is a fluid that does not follow Newton's law of viscosity, that is, it has variable viscosity dependent on stress. In particular, the viscosity of non-Newtonian fluids can change when subjected to force. Ketchup, for example, becomes runnier when shaken and is thus a non-Newtonian fluid.
The viscosity of the sample is then calculated using the following equation: = ˙ where is the sample viscosity, and is the force applied to the sample to pull it apart. Much like the Meissner-type rheometer, the SER rheometer uses a set of two rollers to strain a sample at a given rate. [ 31 ]
A Newtonian fluid is a power-law fluid with a behaviour index of 1, where the shear stress is directly proportional to the shear rate: = These fluids have a constant viscosity, μ, across all shear rates and include many of the most common fluids, such as water, most aqueous solutions, oils, corn syrup, glycerine, air and other gases.
To map the viscosity as a function of all these variables require a large sequence of experiments that generates an even larger set of numbers called measured data, observed data or observations. Prior to, or at the same time as, the experiments is a material property model (or short material model) proposed to describe or explain the observations.