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The term molality is formed in analogy to molarity which is the molar concentration of a solution. The earliest known use of the intensive property molality and of its adjectival unit, the now-deprecated molal, appears to have been published by G. N. Lewis and M. Randall in the 1923 publication of Thermodynamics and the Free Energies of Chemical Substances. [3]
Molar concentration or molarity is most commonly expressed in units of moles of solute per litre of solution. [1] For use in broader applications, it is defined as amount of substance of solute per unit volume of solution, or per unit volume available to the species, represented by lowercase : [2]
By dividing this relation to the molar amount of one component a relation between the apparent molar property of a component and the mixing ratio of components can be obtained. This equation serves as the definition of ~ . The first term is equal to the volume of the same quantity of solvent with no solute, and the second term is the ...
It is also equal to the molar mass (M) divided by the mass density (ρ): = = The molar volume has the SI unit of cubic metres per mole (m 3 /mol), [ 1 ] although it is more typical to use the units cubic decimetres per mole (dm 3 /mol) for gases , and cubic centimetres per mole (cm 3 /mol) for liquids and solids .
The number ratio can be related to the various units for concentration of a solution such as molarity, molality, normality (chemistry), etc. The assumption that solution properties are independent of nature of solute particles is exact only for ideal solutions , which are solutions that exhibit thermodynamic properties analogous to those of an ...
In chemistry, the mass concentration ρ i (or γ i) is defined as the mass of a constituent m i divided by the volume of the mixture V. [1]= For a pure chemical the mass concentration equals its density (mass divided by volume); thus the mass concentration of a component in a mixture can be called the density of a component in a mixture.
In chemistry, concentration is the abundance of a constituent divided by the total volume of a mixture. Several types of mathematical description can be distinguished: mass concentration, molar concentration, number concentration, and volume concentration. [1]
The molar ionic strength, I, of a solution is a function of the concentration of all ions present in that solution. [3]= = where one half is because we are including both cations and anions, c i is the molar concentration of ion i (M, mol/L), z i is the charge number of that ion, and the sum is taken over all ions in the solution.