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Crystal structure of CH 3 NH 3 PbX 3 perovskites (X=I, Br and/or Cl). The methylammonium cation (CH 3 NH 3 +) is surrounded by PbX 6 octahedra. [13]The name "perovskite solar cell" is derived from the ABX 3 crystal structure of the absorber materials, referred to as perovskite structure, where A and B are cations and X is an anion.
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The main obstacle to viable tin perovskite solar cells is the instability of tin's oxidation state Sn 2+, which is easily oxidized to the stabler Sn 4+. [10] In solar cell research, this process is called self-doping, [11] because the Sn 4+ acts as a p-dopant and reduces solar cell efficiency.
Perovskite (pronunciation: / p ə ˈ r ɒ v s k aɪ t /) is a calcium titanium oxide mineral composed of calcium titanate (chemical formula Ca Ti O 3).Its name is also applied to the class of compounds which have the same type of crystal structure as CaTiO 3, known as the perovskite structure, which has a general chemical formula A 2+ B 4+ (X 2−) 3. [6]
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A paper titled "Ageing effects of perovskite solar cells under different environmental factors and electrical load conditions" published in 2018 in the journal [2] corresponded to a paper previously published in the journal Nature Energy as "Systematic investigation of the impact of operation conditions on the degradation behaviour of perovskite solar cells". [3]
Stranks et al. described nanostructured cells using a mixed methylammonium lead halide (CH 3 NH 3 PbI 3− x Cl x) and demonstrated one amorphous thin-film solar cell with an 11.4% conversion efficiency, and another that reached 15.4% using vacuum evaporation. The film thickness of about 500 to 600 nm implies that the electron and hole ...
Since 2009, Miyasaka has been working on research and development of perovskite solar cell, therefore, he won the Clarivate Citation Laureates in 2017. [7] In 2017 Miyasaka was awarded the Hamakawa award for his contribution in photovoltaic science and technology development.