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In chemistry, orbital hybridisation (or hybridization) is the concept of mixing atomic orbitals to form new hybrid orbitals (with different energies, shapes, etc., than the component atomic orbitals) suitable for the pairing of electrons to form chemical bonds in valence bond theory.
In chemistry, isovalent or second order hybridization is an extension of orbital hybridization, the mixing of atomic orbitals into hybrid orbitals which can form chemical bonds, to include fractional numbers of atomic orbitals of each type (s, p, d). It allows for a quantitative depiction of bond formation when the molecular geometry deviates ...
A 3D model of ethyne (), the simplest alkyneIn organic chemistry, an alkyne is an unsaturated hydrocarbon containing at least one carbon—carbon triple bond. [1] The simplest acyclic alkynes with only one triple bond and no other functional groups form a homologous series with the general chemical formula C n H 2n−2.
In fact, the carbon atoms in the single bond need not be of the same hybridization. Carbon atoms can also form double bonds in compounds called alkenes or triple bonds in compounds called alkynes. A double bond is formed with an sp 2-hybridized orbital and a p-orbital that is not involved in the hybridization. A triple bond is formed with an sp ...
Acetylene (systematic name: ethyne) is the chemical compound with the formula C 2 H 2 and structure H−C≡C−H.It is a hydrocarbon and the simplest alkyne. [8] This colorless gas is widely used as a fuel and a chemical building block.
Hybridization is a model that describes how atomic orbitals combine to form new orbitals that better match the geometry of molecules. Atomic orbitals that are similar in energy combine to make hybrid orbitals. For example, the carbon in methane (CH 4) undergoes sp 3 hybridization to form four equivalent orbitals, resulting in a tetrahedral shape.
Propyne exists in equilibrium with propadiene, the mixture of propyne and propadiene being called MAPD: . H 3 CC≡CH ⇌ H 2 C=C=CH 2. The coefficient of equilibrium K eq is 0.22 at 270 °C or 0.1 at 5 °C.
In chemical bonds, an orbital overlap is the concentration of orbitals on adjacent atoms in the same regions of space. Orbital overlap can lead to bond formation. Linus Pauling explained the importance of orbital overlap in the molecular bond angles observed through experimentation; it is the basis for orbital hybridization.