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Oxalic acid's main applications include cleaning or bleaching, especially for the removal of rust (iron complexing agent). Its utility in rust removal agents is due to its forming a stable, water-soluble salt with ferric iron, ferrioxalate ion. Oxalic acid is an ingredient in some tooth whitening products.
It is the sodium salt of oxalic acid. It contains sodium cations Na + and oxalate anions C 2 O 2− 4. It is a white, crystalline, odorless solid, that decomposes above 290 °C. [2] Sodium oxalate can act as a reducing agent, and it may be used as a primary standard for standardizing potassium permanganate (KMnO 4) solutions.
It is necessary to calculate the mass of a solid acid which will react with about 20 cm 3 of this solution (for a titration using a 25 cm 3 burette): suitable solid acids include oxalic acid dihydrate, potassium hydrogen phthalate and potassium hydrogen iodate. The equivalent weights of the three acids 63.04 g, 204.23 g and 389.92 g ...
It can also be prepared by treating oxalic acid with phosphorus pentachloride. [6] [7] Oxalyl chloride is produced commercially from ethylene carbonate. Photochlorination gives the perchloroethylene carbonate C 2 Cl 4 O 2 CO and hydrogen chloride HCl, which is subsequently degraded to oxalyl chloride and phosgene COCl 2: [8] C 2 H 4 O 2 CO + 4 ...
Oxalate (systematic IUPAC name: ethanedioate) is an anion with the chemical formula C 2 O 2− 4.This dianion is colorless. It occurs naturally, including in some foods. It forms a variety of salts, for example sodium oxalate (Na 2 C 2 O 4), and several esters such as dimethyl oxalate ((CH 3) 2 C 2 O 4).
It is an ammonium salt of oxalic acid. It consists of ammonium cations ([NH 4] +) and oxalate anions (C 2 O 2− 4). The structure of ammonium oxalate is ([NH 4] +) 2 [C 2 O 4] 2−. Ammonium oxalate sometimes comes as a monohydrate ([NH 4] 2 C 2 O 4 ·H 2 O). It is a colorless or white salt under standard conditions and is odorless and non ...
A typical titration curve of a diprotic acid, oxalic acid, titrated with a strong base, sodium hydroxide.Both equivalence points are visible. Titrations are often recorded on graphs called titration curves, which generally contain the volume of the titrant as the independent variable and the pH of the solution as the dependent variable (because it changes depending on the composition of the ...
Calcium oxalate (in archaic terminology, oxalate of lime) is a calcium salt of oxalic acid with the chemical formula CaC 2 O 4 or Ca(COO) 2. It forms hydrates CaC 2 O 4 ·nH 2 O, where n varies from 1 to 3. Anhydrous and all hydrated forms are colorless or white.