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Magnesium oxide (Mg O), or magnesia, is a white hygroscopic solid mineral that occurs naturally as periclase and is a source of magnesium (see also oxide). It has an empirical formula of MgO and consists of a lattice of Mg 2+ ions and O 2− ions held together by ionic bonding .
This often causes ionic compounds to be very stable. Ionic bonds have high bond energy. Bond energy is the mean amount of energy required to break the bond in the gaseous state. Most ionic compounds exist in the form of a crystal structure, in which the ions occupy the corners of the crystal.
Forming an ionic bond, Li and F become Li + and F − ions. An ion (/ ˈ aɪ. ɒ n,-ən /) [1] is an atom or molecule with a net electrical charge. The charge of an electron is considered to be negative by convention and this charge is equal and opposite to the charge of a proton, which is considered to be positive by convention. The net charge ...
Magnesium oxide is the end product of the thermal decomposition of some magnesium compounds and is usually prepared by igniting carbonates or hydroxides. Magnesium hydroxide is a strong electrolyte, which can be obtained by the reaction of a soluble magnesium salt and sodium hydroxide.
The strength of the M-O bond tends to increase with the charge and decrease as the size of the metal ion increases. In fact there is a very good linear correlation between hydration enthalpy and the ratio of charge squared to ionic radius, z 2 /r. [4] For ions in solution Shannon's "effective ionic radius" is the measure most often used. [5]
For typical ionic solids, the cations are smaller than the anions, and each cation is surrounded by coordinated anions which form a polyhedron.The sum of the ionic radii determines the cation-anion distance, while the cation-anion radius ratio + / (or /) determines the coordination number (C.N.) of the cation, as well as the shape of the coordinated polyhedron of anions.
In solution. Mg 2+ Disodium phosphate is a very selective reagent for magnesium ions and, in the presence of ammonium salts and ammonia, forms a white precipitate of ammonium magnesium phosphate. Mg 2+ + NH 3 + Na 2 HPO 4 → (NH 4)MgPO 4 + 2Na + Ca 2+ Ca 2+ forms a white precipitate with ammonium oxalate. Calcium oxalate is insoluble in water ...
Periclase is a magnesium mineral that occurs naturally in contact metamorphic rocks and is a major component of most basic refractory bricks. It is a cubic form of magnesium oxide (Mg O). In nature it usually forms a solid solution with wüstite (FeO) and is then referred to as ferropericlase or magnesiowüstite. [6]