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  2. Atom transfer radical polymerization - Wikipedia

    en.wikipedia.org/wiki/Atom_Transfer_Radical...

    It provides increased control of molecular weight, molecular architecture and polymer composition while maintaining a low polydispersity (1.05-1.2). The halogen remaining at the end of the polymer chain after polymerization allows for facile post-polymerization chain-end modification into different reactive functional groups.

  3. Zaytsev's rule - Wikipedia

    en.wikipedia.org/wiki/Zaytsev's_rule

    Zaytsev's rule. In organic chemistry, Zaytsev's rule (or Zaitsev's rule, Saytzeff's rule, Saytzev's rule) is an empirical rule for predicting the favored alkene product (s) in elimination reactions. While at the University of Kazan, Russian chemist Alexander Zaytsev studied a variety of different elimination reactions and observed a general ...

  4. Step-growth polymerization - Wikipedia

    en.wikipedia.org/wiki/Step-growth_polymerization

    Step-growth polymerization is a random process so we can use statistics to calculate the probability of finding a chain with x-structural units ("x-mer") as a function of time or conversion. Probability that an 'A' functional group has reacted. Probability of finding an 'A' unreacted.

  5. Molar mass - Wikipedia

    en.wikipedia.org/wiki/Molar_mass

    M N−1. In chemistry, the molar mass (M) (sometimes called molecular weight or formula weight, but see related quantities for usage) of a chemical compound is defined as the ratio between the mass and the amount of substance (measured in moles) of any sample of the compound. [1] The molar mass is a bulk, not molecular, property of a substance.

  6. Molecular mass - Wikipedia

    en.wikipedia.org/wiki/Molecular_mass

    The molecular mass (m) is the mass of a given molecule. Units of daltons (Da) are often used. [1] Different molecules of the same compound may have different molecular masses because they contain different isotopes of an element. The derived quantity relative molecular mass is the unitless ratio of the mass of a molecule to the atomic mass ...

  7. Substitution reaction - Wikipedia

    en.wikipedia.org/wiki/Substitution_reaction

    The two reactions are named according tho their rate law, with S N 1 having a first-order rate law, and S N 2 having a second-order. [2] S N 1 reaction mechanism occurring through two steps. The S N 1 mechanism has two steps. In the first step, the leaving group departs, forming a carbocation (C +). In the second step, the nucleophilic reagent ...

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  9. Molar mass distribution - Wikipedia

    en.wikipedia.org/wiki/Molar_mass_distribution

    In polymer chemistry, the molar mass distribution (or molecular weight distribution) describes the relationship between the number of moles of each polymer species (Ni) and the molar mass (Mi) of that species. [1] In linear polymers, the individual polymer chains rarely have exactly the same degree of polymerization and molar mass, and there is ...