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In aqueous solutions, hydrogen peroxide forms a eutectic mixture, exhibiting freezing-point depression down as low as –56 °C; pure water has a freezing point of 0 °C and pure hydrogen peroxide of –0.43 °C. The boiling point of the same mixtures is also depressed in relation with the mean of both boiling points (125.1 °C).
Boiling point (°C) K b (°C⋅kg/mol) Freezing point (°C) K f (°C⋅kg/mol) Data source; Aniline: 184.3 3.69 –5.96 –5.87 K b & K f [1] Lauric acid:
This page contains tables of azeotrope data for various binary and ternary mixtures of solvents. The data include the composition of a mixture by weight (in binary azeotropes, when only one fraction is given, it is the fraction of the second component), the boiling point (b.p.) of a component, the boiling point of a mixture, and the specific gravity of the mixture.
High-test peroxide (HTP) is a highly concentrated (85 to 98%) solution of hydrogen peroxide, with the remainder consisting predominantly of water. In contact with a catalyst, it decomposes into a high-temperature mixture of steam and oxygen, with no remaining liquid water.
A sudden increase in temperature can also lead to a violent boiling of the extremely acidic solution. Solutions made using hydrogen peroxide at concentrations greater than 50 wt % may cause an explosion. [7] The 1:1 acid–peroxide mixtures will also create an explosion risk even when using common 30 wt. % hydrogen peroxide. [8]
For the preparation of the complex, urea is dissolved in 30% hydrogen peroxide (molar ratio 2:3) at temperatures below 60 °C. upon cooling this solution, hydrogen peroxide–urea precipitates in the form of small platelets. [2] Akin to water of crystallization, hydrogen peroxide cocrystallizes with urea with the stoichiometry of 1:1.
Hydroxylamine can be an explosive, with a theoretical decomposition energy of about 5 kJ/g, and aqueous solutions above 80% can be easily detonated by detonator or strong heating under confinement. [ 16 ] [ 17 ] At least two factories dealing in hydroxylamine have been destroyed since 1999 with loss of life. [ 33 ]
An aqueous solution of lead(II) acetate is a byproduct of the process used in the cleaning and maintenance of stainless steel firearm suppressors (silencers) and compensators when using a 1:1 ratio of hydrogen peroxide and white vinegar (acetic acid). The solution is agitated by the bubbling action of the hydrogen peroxide, with the main ...