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The "(s)" notation indicates temperature of solid/vapor equilibrium. Otherwise the data is temperature of liquid/vapor equilibrium. log 10 of Acetonitrile vapor pressure.
Acetonitrile is used mainly as a solvent in the purification of butadiene in refineries. Specifically, acetonitrile is fed into the top of a distillation column filled with hydrocarbons including butadiene, and as the acetonitrile falls down through the column, it absorbs the butadiene which is then sent from the bottom of the tower to a second separating tower.
Values are given in terms of temperature necessary to reach the specified pressure. Valid results within the quoted ranges from most equations are included in the table for comparison. A conversion factor is included into the original first coefficients of the equations to provide the pressure in pascals (CR2: 5.006, SMI: -0.875).
This page contains tables of azeotrope data for various binary and ternary mixtures of solvents. The data include the composition of a mixture by weight (in binary azeotropes, when only one fraction is given, it is the fraction of the second component), the boiling point (b.p.) of a component, the boiling point of a mixture, and the specific gravity of the mixture.
Vapor pressure of acetone based on formula, = + from Lange's Handbook of Chemistry, 10th ed. vapor pressure of acetone (log scale) based on formula, log 10 P m m H g = 7.02447 − 1161.0 224 + T {\displaystyle \scriptstyle \log _{10}P_{mmHg}=7.02447-{\frac {1161.0}{224+T}}} from Lange's Handbook of Chemistry , 10th ed.
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In that context, a lighter component means a component with a lower boiling point (or a higher vapor pressure) and a heavier component means a component with a higher boiling point (or a lower vapor pressure). Thus, for the distillation of any multi-component mixture, the relative volatility is often defined as
The aqueous solution consists of acrylonitrile, acetonitrile, hydrocyanic acid, and ammonium sulfate (from excess ammonia). A recovery column removes bulk water, and acrylonitrile and acetonitrile are separated by distillation. One of the first useful catalysts was bismuth phosphomolybdate (Bi 9 PMo 12 O 52) supported on silica. [11]