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Refractometry is the analytical method of measuring substances' refractive index (one of their fundamental physical properties) in order to, for instance, assess their composition or purity. A refractometer is the instrument used to measure refractive index ("RI"). Although refractometers are best known for measuring liquids, they are also used ...
Refractometry [ edit ] Standard refractometers measure the extent of light refraction (as part of a refractive index) of transparent substances in either a liquid this is then used in order to identify a liquid sample, analyze the sample's purity, and determine the amount or concentration of dissolved substances within the sample.
Among these are methods for determination of dry solids content by polarimetry, densimetry and refractometry, color (extinction coefficient at 420 nm), reducing sugars, and the presence of metals such as arsenic and copper.
Refraction at interface. Many materials have a well-characterized refractive index, but these indices often depend strongly upon the frequency of light, causing optical dispersion.
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The most general form of Cauchy's equation is n ( λ ) = A + B λ 2 + C λ 4 + ⋯ , {\displaystyle n(\lambda )=A+{\frac {B}{\lambda ^{2}}}+{\frac {C}{\lambda ^{4}}}+\cdots ,} where n is the refractive index, λ is the wavelength, A , B , C , etc., are coefficients that can be determined for a material by fitting the equation to measured ...
A diagram of the general front-view of a differential refractometer. A differential refractometer (DRI), or refractive index detector (RI or RID) is a detector that measures the refractive index of an analyte relative to the solvent.
A. R. Forouhi and I. Bloomer deduced dispersion equations for the refractive index, n, and extinction coefficient, k, which were published in 1986 [1] and 1988. [2] The 1986 publication relates to amorphous materials, while the 1988 publication relates to crystalline.