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A calibration curve plot showing limit of detection (LOD), limit of quantification (LOQ), dynamic range, and limit of linearity (LOL).. In analytical chemistry, a calibration curve, also known as a standard curve, is a general method for determining the concentration of a substance in an unknown sample by comparing the unknown to a set of standard samples of known concentration. [1]
The calibration curve that does not use the internal standard method ignores the uncertainty between measurements. The coefficient of determination (R 2) for this plot is 0.9985. In the calibration curve that uses the internal standard, the y-axis is the ratio of the nickel signal to the yttrium signal.
The Steinhart–Hart equation is a model relating the varying electrical resistance of a semiconductor to its varying temperatures. The equation is. where. are the Steinhart–Hart coefficients, which are characteristics specific to the bulk semiconductor material over a given temperature range of interest.
The Mark–Houwink equation, also known as the Mark–Houwink–Sakurada equation or the Kuhn–Mark–Houwink–Sakurada equation or the Landau–Kuhn–Mark–Houwink–Sakurada equation or the Mark-Chrystian equation gives a relation between intrinsic viscosity and molecular weight : [1][2] From this equation the molecular weight of a ...
In statistics, the coefficient of determination, denoted R2 or r2 and pronounced "R squared", is the proportion of the variation in the dependent variable that is predictable from the independent variable (s). It is a statistic used in the context of statistical models whose main purpose is either the prediction of future outcomes or the ...
The Standard addition method, often used in analytical chemistry, quantifies the analyte present in an unknown. This method is useful for analyzing complex samples where a matrix effect interferes with the analyte signal. In comparison to the calibration curve method, the standard addition method has the advantage of the matrices of the unknown ...
Radiocarbon calibration. Radiocarbon dating measurements produce ages in "radiocarbon years", which must be converted to calendar ages by a process called calibration. Calibration is needed because the atmospheric 14. C: 12. C ratio, which is a key element in calculating radiocarbon ages, has not been constant historically.
Standard solution. In analytical chemistry, a standard solution (titrant or titrator) is a solution containing an accurately known concentration. Standard solutions are generally prepared by dissolving a solute of known mass into a solvent to a precise volume, or by diluting a solution of known concentration with more solvent. [1]
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