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8 (cyclooctatetraenide anion), with ten π electrons obeys the 4n + 2 rule for n = 2 and is planar, while the 1,4-dimethyl derivative of the dication, with six π electrons, is also believed to be planar and aromatic. [8] The Cyclononatetraenide anion (C 9 H – 9) is the largest all-cis monocyclic annulene/annulenyl system that is planar and ...
Heteroarenes are aromatic compounds, where at least one methine or vinylene (-C= or -CH=CH-) group is replaced by a heteroatom: oxygen, nitrogen, or sulfur. [3] Examples of non-benzene compounds with aromatic properties are furan, a heterocyclic compound with a five-membered ring that includes a single oxygen atom, and pyridine, a heterocyclic compound with a six-membered ring containing one ...
Homoaromaticity, in organic chemistry, refers to a special case of aromaticity in which conjugation is interrupted by a single sp 3 hybridized carbon atom. Although this sp 3 center disrupts the continuous overlap of p-orbitals, traditionally thought to be a requirement for aromaticity, considerable thermodynamic stability and many of the spectroscopic, magnetic, and chemical properties ...
9-Anthracenemethanol is the derivative of anthracene with a hydroxymethyl group (CH 2 OH) attached to the 9-position. It is a colorless solid that is soluble in ordinary organic solvents. The compound can be prepared by hydrogenation of 9-anthracenecarboxaldehyde. It is a versatile precursor to supramolecular assemblies. [1]
Methanol is primarily converted to formaldehyde, which is widely used in many areas, especially polymers. The conversion entails oxidation: 2 CH 3 OH + O 2 → 2 CH 2 O + 2 H 2 O. Acetic acid can be produced from methanol. The Cativa process converts methanol into acetic acid. [35] Methanol and isobutene are combined to give methyl tert-butyl ...
In contrast to the rarity of Möbius aromatic ground state molecular systems, there are many examples of pericyclic transition states that exhibit Möbius aromaticity. The classification of a pericyclic transition state as either Möbius or Hückel topology determines whether 4N or 4N + 2 electrons are required to make the transition state aromatic or antiaromatic, and therefore, allowed or ...
The best known of these is the ternary azeotrope formed by 30% acetone, 47% chloroform, and 23% methanol, which boils at 57.5 °C. Each pair of these constituents forms a binary azeotrope, but chloroform/methanol and acetone/methanol both form positive azeotropes while chloroform/acetone forms a negative azeotrope.
Glauber's salt – sodium sulfate.Na 2 SO 4; Sal alembroth – salt composed of chlorides of ammonium and mercury.; Sal ammoniac – ammonium chloride.; Sal petrae (Med. Latin: "stone salt")/salt of petra/saltpetre/nitrate of potash – potassium nitrate, KNO 3, typically mined from covered dungheaps.