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Fluorine's first ionization energy is third-highest among all elements, behind helium and neon, [16] which complicates the removal of electrons from neutral fluorine atoms. It also has a high electron affinity , second only to chlorine , [ 17 ] and tends to capture an electron to become isoelectronic with the noble gas neon; [ 3 ] it has the ...
The main uses of fluoride, in terms of volume, are in the production of cryolite, Na 3 AlF 6. It is used in aluminium smelting. Formerly, it was mined, but now it is derived from hydrogen fluoride. Fluorite is used on a large scale to separate slag in steel-making. Mined fluorite (CaF 2) is a commodity chemical used in steel-making.
Fluorine forms compounds with all elements except neon and helium. In particular, it forms binary compounds , named fluorides , with all said elements except argon . All of the elements up to einsteinium , element 99, have been checked except for astatine and francium , [ 24 ] and fluorine is also known to form compounds with mendelevium ...
Fluorine compounds are highly amenable to nuclear magnetic resonance (NMR), because fluorine-19 has a nuclear spin of 1 ⁄ 2, a high nuclear magnetic moment, and a high magnetogyric ratio. Fluorine compounds typically have a fast NMR relaxation , which enables the use of fast averaging to obtain a signal-to-noise ratio similar to hydrogen-1 ...
Moissan's fluorine cell, from his 1887 publication. Fluorine is a relatively new element in human applications. In ancient times, only minor uses of fluorine-containing minerals existed. The industrial use of fluorite, fluorine's source mineral, was first described by early scientist Georgius Agricola in the 16th century, in the context of ...
Fluorite also gave the name to its constitutive element fluorine. [3] Currently, the word "fluorspar" is most commonly used for fluorite as an industrial and chemical commodity, while "fluorite" is used mineralogically and in most other senses.
At 400 ppb, fluorine is estimated to be the 24th most common element in the universe. It is comparably rare for a light element (elements tend to be more common the lighter they are). All of the elements from atomic number 6 (carbon) to atomic number 12 (magnesium) are hundreds or thousands of times more common than fluorine except for 11 (sodium).
CHCl 3 + 2 HF → CHClF 2 + 2 HCl. Pyrolysis of chlorodifluoromethane (at 550-750 °C) yields TFE. HF is a reactive solvent in the electrochemical fluorination of organic compounds. In this approach, HF is oxidized in the presence of a hydrocarbon and the fluorine replaces C–H bonds with C–F bonds.