Search results
Results From The WOW.Com Content Network
Systematic errors in the measurement of experimental quantities leads to bias in the derived quantity, the magnitude of which is calculated using Eq(6) or Eq(7). However, there is also a more subtle form of bias that can occur even if the input, measured, quantities are unbiased; all terms after the first in Eq(14) represent this bias.
Knowing the analytical concentrations of reactants initially in the reaction vessel and in the burette, all analytical concentrations can be derived as a function of the volume (or mass) of titrant added. The equilibrium constants may be derived by best-fitting of the experimental data with a chemical model of the equilibrium system.
Any non-linear differentiable function, (,), of two variables, and , can be expanded as + +. If we take the variance on both sides and use the formula [11] for the variance of a linear combination of variables (+) = + + (,), then we obtain | | + | | +, where is the standard deviation of the function , is the standard deviation of , is the standard deviation of and = is the ...
Stability is a measure of the sensitivity to rounding errors of a given numerical procedure; by contrast, the condition number of a function for a given problem indicates the inherent sensitivity of the function to small perturbations in its input and is independent of the implementation used to solve the problem. [5] [6]
The earliest reference to a similar formula appears to be Armstrong (1985, p. 348), where it is called "adjusted MAPE" and is defined without the absolute values in the denominator. It was later discussed, modified, and re-proposed by Flores (1986).
Systematic errors which change during an experiment are easier to detect. Measurements indicate trends with time rather than varying randomly about a mean. Drift is ...
In metrology, measurement uncertainty is the expression of the statistical dispersion of the values attributed to a quantity measured on an interval or ratio scale.. All measurements are subject to uncertainty and a measurement result is complete only when it is accompanied by a statement of the associated uncertainty, such as the standard deviation.
This physical chemistry -related article is a stub. You can help Wikipedia by expanding it.