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In physical chemistry, the Arrhenius equation is a formula for the temperature dependence of reaction rates.The equation was proposed by Svante Arrhenius in 1889, based on the work of Dutch chemist Jacobus Henricus van 't Hoff who had noted in 1884 that the van 't Hoff equation for the temperature dependence of equilibrium constants suggests such a formula for the rates of both forward and ...
If we condense the skew entries into a vector, (x,y,z), then we produce a 90° rotation around the x-axis for (1, 0, 0), around the y-axis for (0, 1, 0), and around the z-axis for (0, 0, 1). The 180° rotations are just out of reach; for, in the limit as x → ∞, (x, 0, 0) does approach a 180° rotation around the x axis, and similarly for ...
Theoretical chemistry requires quantities from core physics, such as time, volume, temperature, and pressure.But the highly quantitative nature of physical chemistry, in a more specialized way than core physics, uses molar amounts of substance rather than simply counting numbers; this leads to the specialized definitions in this article.
Isomers are types of molecules that share a chemical formula but have difference geometries, resulting in different properties: A pure substance is composed of only one type of isomer of a molecule (all have the same geometrical structure).
Rotation around an axis (C n) consists of rotating the molecule around a specific axis by a specific angle. It is rotation through the angle 360°/ n , where n is an integer, about a rotation axis. For example, if a water molecule rotates 180° around the axis that passes through the oxygen atom and between the hydrogen atoms, it is in the same ...
VSEPR theory is used to predict the arrangement of electron pairs around central atoms in molecules, especially simple and symmetric molecules. A central atom is defined in this theory as an atom which is bonded to two or more other atoms, while a terminal atom is bonded to only one other atom.
In mathematics, reflection through the origin refers to the point reflection of Euclidean space R n across the origin of the Cartesian coordinate system. Reflection through the origin is an orthogonal transformation corresponding to scalar multiplication by − 1 {\displaystyle -1} , and can also be written as − I {\displaystyle -I} , where I ...
And these systems of the mathematics convention may measure the azimuthal angle counterclockwise (i.e., from the south direction x-axis, or 180°, towards the east direction y-axis, or +90°)—rather than measure clockwise (i.e., from the north direction x-axis, or 0°, towards the east direction y-axis, or +90°), as done in the horizontal ...