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  2. Energy profile (chemistry) - Wikipedia

    en.wikipedia.org/wiki/Energy_profile_(chemistry)

    Figure 13: An energy profile diagram demonstrating the effect of a catalyst for the generic exothermic reaction of X + Y →Z. The catalyst offers an alternate reaction pathway (shown in red) where the rate determining step has a smaller ΔG≠. The relative thermodynamic stabilities remain the same.

  3. Endothermic process - Wikipedia

    en.wikipedia.org/wiki/Endothermic_process

    The opposite of an endothermic process is an exothermic process, one that releases or "gives out" energy, usually in the form of heat and sometimes as electrical energy. [1] Thus, endo in endothermic refers to energy or heat going in, and exo in exothermic refers to energy or heat going out. In each term (endothermic and exothermic) the prefix ...

  4. Enthalpy change of solution - Wikipedia

    en.wikipedia.org/wiki/Enthalpy_change_of_solution

    The energy released by the solvation of the ammonium ions and nitrate ions is less than the energy absorbed in breaking up the ammonium nitrate ionic lattice and the attractions between water molecules. Dissolving potassium hydroxide is exothermic, as more energy is released during solvation than is used in breaking up the solute and solvent.

  5. Exothermic reaction - Wikipedia

    en.wikipedia.org/wiki/Exothermic_reaction

    An energy profile of an exothermic reaction. In an exothermic reaction, by definition, the enthalpy change has a negative value: ΔH = H products - H reactants < 0. where a larger value (the higher energy of the reactants) is subtracted from a smaller value (the lower energy of the products). For example, when hydrogen burns: 2H 2 (g) + O 2 (g ...

  6. Exothermic process - Wikipedia

    en.wikipedia.org/wiki/Exothermic_process

    The opposite of an exothermic process is an endothermic process, one that absorbs energy, usually in the form of heat. [2] The concept is frequently applied in the physical sciences to chemical reactions where chemical bond energy is converted to thermal energy (heat).

  7. Van 't Hoff equation - Wikipedia

    en.wikipedia.org/wiki/Van_'t_Hoff_equation

    Van 't Hoff plot for an endothermic reaction. For an endothermic reaction, heat is absorbed, making the net enthalpy change positive. Thus, according to the definition of the slope: =, When the reaction is endothermic, Δ r H > 0 (and the gas constant R > 0), so

  8. Thermal decomposition - Wikipedia

    en.wikipedia.org/wiki/Thermal_decomposition

    The reaction is usually endothermic as heat is required to break chemical bonds in the compound undergoing decomposition. If decomposition is sufficiently exothermic, a positive feedback loop is created producing thermal runaway and possibly an explosion or other chemical reaction. Thermal decomposition is a chemical reaction where heat is a ...

  9. Hammond's postulate - Wikipedia

    en.wikipedia.org/wiki/Hammond's_postulate

    This can be explained with reference to potential energy diagrams: Energy diagrams showing how to interpret Hammond's Postulate. In case (a), which is an exothermic reaction, the energy of the transition state is closer in energy to that of the reactant than that of the intermediate or the product.