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Temperature-dependency of the heats of vaporization for water, methanol, benzene, and acetone. In thermodynamics, the enthalpy of vaporization (symbol ∆H vap), also known as the (latent) heat of vaporization or heat of evaporation, is the amount of energy that must be added to a liquid substance to transform a quantity of that substance into a gas.
λ v = latent heat of vaporization (J kg −1) γ = psychrometric constant (Pa K −1) which (if the SI units in parentheses are used) will give the evaporation E mass in units of kg/(m 2 ·s), kilograms of water evaporated every second for each square meter of area. Remove λ to obviate that this is fundamentally an energy balance.
The terms sensible heat and latent heat refer to energy transferred between a body and its surroundings, defined by the occurrence or non-occurrence of temperature change; they depend on the properties of the body. Sensible heat is sensed or felt in a process as a change in the body's temperature.
λ v = Latent heat of vaporization. The energy required per unit mass of water vaporized. (J g −1) L v = Volumetric latent heat of vaporization. The energy required per unit volume of water vaporized. (L v = 2453 MJ m −3) E = Mass water evapotranspiration rate (g s −1 m −2) ET = Water volume evapotranspired (mm s −1)
Heat transfer can either occur as sensible heat (differences in temperature without evapotranspiration) or latent heat (the energy required during a change of state, without a change in temperature). The Bowen ratio is generally used to calculate heat lost (or gained) in a substance; it is the ratio of energy fluxes from one state to another by ...
: latent heat of evaporation (2400 kJ/kg at 25°C to 2600 kJ/kg at −40°C) c p d {\displaystyle c_{pd}} : specific heat at constant pressure for air (≈ 1004 J/(kg·K)) Tables exist for exact values of the last two coefficients.
L is the latent heat of vaporization at the temperature T, T C is the critical temperature, L 0 is the parameter that is equal to the heat of vaporization at zero temperature (T → 0), tanh is the hyperbolic tangent function. This equation was obtained in 1955 by Yu. I. Shimansky, at first empirically, and later derived theoretically.
J.A. Dean (ed.), Lange's Handbook of Chemistry (15th Edition), McGraw-Hill, 1999; Section 6, Thermodynamic Properties; Table 6.4, Heats of Fusion, Vaporization, and Sublimation and Specific Heat at Various Temperatures of the Elements and Inorganic Compounds