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GFAA spectrometry instruments have the following basic features: 1. a source of light (lamp) that emits resonance line radiation; 2. an atomization chamber (graphite tube) in which the sample is vaporized; 3. a monochromator for selecting only one of the characteristic wavelengths (visible or ultraviolet) of the element of interest; 4. a detector, generally a photomultiplier tube (light ...
The specificity of absorption spectra allows compounds to be distinguished from one another in a mixture, making absorption spectroscopy useful in wide variety of applications. For instance, Infrared gas analyzers can be used to identify the presence of pollutants in the air, distinguishing the pollutant from nitrogen, oxygen, water, and other ...
In molecular spectroscopy, a Jablonski diagram is a diagram that illustrates the electronic states and often the vibrational levels of a molecule, and also the transitions between them. The states are arranged vertically by energy and grouped horizontally by spin multiplicity . [ 1 ]
An overview of absorption of electromagnetic radiation.This example shows the general principle using visible light as a specific example. A white light source—emitting light of multiple wavelengths—is focused on a sample (the pairs of complementary colors are indicated by the yellow dotted lines).
Spectroelectrochemical cell: device in which the solution and the system of three electrodes is located, avoiding possible interference in the optical path. [7] It is the link between the electrochemistry and the UV-Vis absorption spectroscopy. [3] Devices to conduct the radiation beam: lenses, mirrors and/or optical fibers. The last ones ...
Saturated absorption spectroscopy measures the transition frequency of an atom or molecule between its ground state and an excited state. In saturated absorption spectroscopy, two counter-propagating, overlapped laser beams are sent through a sample of atomic gas.
X-ray absorption spectroscopy (XAS) is a widely used technique for determining the local geometric and/or electronic structure of matter. [1] The experiment is usually performed at synchrotron radiation facilities, which provide intense and tunable X-ray beams. Samples can be in the gas phase, solutions, or solids. [2]
The dominant physical process in x-ray absorption is one where the absorbed photon ejects a core photoelectron from the absorbing atom, leaving behind a core hole. [1] The ejected photoelectron's energy will be equal to that of the absorbed photon minus the binding energy of the initial core state.