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In physical chemistry and chemical engineering, extent of reaction is a quantity that measures the extent to which the reaction has proceeded. Often, it refers specifically to the value of the extent of reaction when equilibrium has been reached.
Transformation into negation normal form can increase the size of a formula only linearly: the number of occurrences of atomic formulas remains the same, the total number of occurrences of and is unchanged, and the number of occurrences of in the normal form is bounded by the length of the original formula. A formula in negation normal form can ...
Double negation elimination occurs in classical logics but not in intuitionistic logic. In the context of a formula in the conjunctive normal form, a literal is pure if the literal's complement does not appear in the formula. In Boolean functions, each separate occurrence of a variable, either in inverse or uncomplemented form, is a literal.
Partition coefficients can be measured experimentally in various ways (by shake-flask, HPLC, etc.) or estimated by calculation based on a variety of methods (fragment-based, atom-based, etc.). If a substance is present as several chemical species in the partition system due to association or dissociation, each species is assigned its own K ow ...
A molecule is said to have a positive oxygen balance if it contains more oxygen than is needed and a negative oxygen balance if it contains less oxygen than is needed. [2] An explosive with a negative oxygen balance will lead to incomplete combustion, which commonly produces carbon monoxide, which is a toxic gas. Explosives with negative or ...
Negative hyperconjugation is seldom observed, though it can be most commonly observed when the σ *-orbital is located on certain C–F or C–O bonds. [ 3 ] [ 4 ] In negative hyperconjugation, the electron density flows in the opposite direction (from a π- or p-orbital to an empty σ * -orbital) than it does in the more common ...
In logic, negation, also called the logical not or logical complement, is an operation that takes a proposition to another proposition "not ", written , , ′ [1] or ¯. [citation needed] It is interpreted intuitively as being true when is false, and false when is true.
In electrochemistry, the Nernst equation is a chemical thermodynamical relationship that permits the calculation of the reduction potential of a reaction (half-cell or full cell reaction) from the standard electrode potential, absolute temperature, the number of electrons involved in the redox reaction, and activities (often approximated by concentrations) of the chemical species undergoing ...