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The Laporte rule is a rule that explains the intensities of absorption spectra for chemical species. It is a selection rule that rigorously applies to atoms, and to molecules that are centrosymmetric, i.e. with an inversion centre. It states that electronic transitions that conserve parity are forbidden. Thus transitions between two states that ...
The Laporte rule is a selection rule formally stated as follows: In a centrosymmetric environment, transitions between like atomic orbitals such as s-s, p-p, d-d, or f-f, transitions are forbidden. The Laporte rule (law) applies to electric dipole transitions, so the operator has u symmetry (meaning ungerade, odd).
The lattice must also be stable under chemical and photochemical conditions, as these are the environments the conversion will take place within. Finally, this host lattice ought to have low symmetry, allowing for a slight relaxation of the Laporte selection rules. The normally forbidden transitions lead to an increase in the f-f intermixing ...
Scientific method – body of techniques for investigating phenomena and acquiring new knowledge, as well as for correcting and integrating previous knowledge. It is based on observable , empirical , reproducible , measurable evidence , and subject to the laws of reasoning .
Heuer outlines the ACH process in considerable depth in his book, Psychology of Intelligence Analysis. [1] It consists of the following steps: Hypothesis – The first step of the process is to identify all potential hypotheses, preferably using a group of analysts with different perspectives to brainstorm the possibilities.
The pps sampling results in a fixed sample size n (as opposed to Poisson sampling which is similar but results in a random sample size with expectancy of n). When selecting items with replacement the selection procedure is to just draw one item at a time (like getting n draws from a multinomial distribution with N elements, each with their own ...
Otto Laporte (July 23, 1902 – March 28, 1971) was a German-born American physicist who made contributions to quantum mechanics, electromagnetic wave propagation theory, spectroscopy, and fluid dynamics. His name is lent to the Laporte rule in spectroscopy and to the Otto Laporte Award of the American Physical Society. [1]
In mathematics, a selection principle is a rule asserting the possibility of obtaining mathematically significant objects by selecting elements from given sequences of sets. The theory of selection principles studies these principles and their relations to other mathematical properties.