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Critical Radius Ratio. This diagram is for octahedral interstices (coordination number six): 4 anions in the plane shown, 1 above the plane and 1 below. The stability limit is at r C /r A = 0.414. The radius ratio rule defines a critical radius ratio for different crystal structures, based on their coordination geometry. [1]
where is the void ratio, is the porosity, V V is the volume of void-space (gases and liquids), V S is the volume of solids, and V T is the total (or bulk) volume. This figure is relevant in composites , in mining (particular with regard to the properties of tailings ), and in soil science .
The volume of a tetrahedron can be obtained in many ways. It can be given by using the formula of the pyramid's volume: =. where is the base' area and is the height from the base to the apex. This applies for each of the four choices of the base, so the distances from the apices to the opposite faces are inversely proportional to the areas of ...
Void content in composites is represented as a ratio, also called void ratio, where the volume of voids, solid material, and bulk volume are taken into account.Void ratio can be calculated by the formula below where e is the void ratio of the composite, V v is the volume of the voids, and V t is the volume of the bulk material.
Porosity or void fraction is a measure of the void (i.e. "empty") spaces in a material, and is a fraction of the volume of voids over the total volume, between 0 and 1, or as a percentage between 0% and 100%. Strictly speaking, some tests measure the "accessible void", the total amount of void space accessible from the surface (cf. closed-cell ...
The tetrahedral void is smaller in size and could fit an atom with a radius 0.225 times the size of the atoms making up the lattice. An octahedral void could fit an atom with a radius 0.414 times the size of the atoms making up the lattice. [1] An atom that fills this empty space could be larger than this ideal radius ratio, which would lead to ...
An octahedron may then form with a radius ratio greater than or equal to 0.414, but as the ratio rises above 0.732, a cubic geometry becomes more stable. This explains why Na + in NaCl with a radius ratio of 0.55 has octahedral coordination, whereas Cs + in CsCl with a radius ratio of 0.93 has cubic coordination.
Porosity or void fraction is a measure of the void (i.e., "empty") spaces in a material, and is a fraction of the volume of voids over the total volume, between 0 and 1, or as a percentage between 0 and 100%.