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The term bond-dissociation energy is similar to the related notion of bond-dissociation enthalpy (or bond enthalpy), which is sometimes used interchangeably.However, some authors make the distinction that the bond-dissociation energy (D 0) refers to the enthalpy change at 0 K, while the term bond-dissociation enthalpy is used for the enthalpy change at 298 K (unambiguously denoted DH° 298).
The bond dissociation energy (enthalpy) [4] is also referred to as bond disruption energy, bond energy, bond strength, or binding energy (abbreviation: BDE, BE, or D). It is defined as the standard enthalpy change of the following fission: R—X → R + X. The BDE, denoted by Dº(R—X), is usually derived by the thermochemical equation,
The Van 't Hoff equation relates the change in the equilibrium constant, K eq, of a chemical reaction to the change in temperature, T, given the standard enthalpy change, Δ r H ⊖, for the process. The subscript r {\displaystyle r} means "reaction" and the superscript ⊖ {\displaystyle \ominus } means "standard".
The pure component's molar volume and molar enthalpy are equal to the corresponding partial molar quantities because there is no volume or internal energy change on mixing for an ideal solution. The molar volume of a mixture can be found from the sum of the excess volumes of the components of a mixture:
Standard enthalpy of hydrogenation is defined as the enthalpy change observed when one mole of an unsaturated compound reacts with an excess of hydrogen to become fully saturated. The hydrogenation of one mole of acetylene yields ethane as a product and is described by the equation C 2 H 2 (g) + 2 H 2 (g) → C 2 H 6 (g).
The transition states for chemical reactions are proposed to have lifetimes near 10 −13 seconds, on the order of the time of a single bond vibration. No physical or spectroscopic method is available to directly observe the structure of the transition state for enzymatic reactions, yet transition state structure is central to understanding ...
The change in enthalpy for a reaction can be calculated from the enthalpies of formation of the reactants and the products; Elements in their standard states make no contribution to the enthalpy calculations for the reaction, since the enthalpy of an element in its standard state is zero.
Enthalpy of atomization is the amount of enthalpy change when bonds of the compound are broken and the component atoms are separated into single atoms ( or monoatom). Enthalpy of atomization is denoted by the symbol ΔH at. The enthalpy change of atomization of gaseous H 2 O is, for example, the sum of the HO–H and H–OH bond dissociation ...