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This work provides site-centred radial charge densities of the ions' interacting atoms (to approximate the electrostatic potential energy of interaction), and these appear to quantitatively correlate with many reported Hofmeister series for electrolyte properties, reaction rates and macromolecular stability (such as polymer solubility, and ...
The Lennard-Jones Potential is a mathematically simple model for the interaction between a pair of atoms or molecules. [3] [4] One of the most common forms is = [() ()] where ε is the depth of the potential well, σ is the finite distance at which the inter-particle potential is zero, r is the distance between the particles.
In theoretical chemistry, Specific ion Interaction Theory (SIT theory) is a theory used to estimate single-ion activity coefficients in electrolyte solutions at relatively high concentrations. [ 1 ] [ 2 ] It does so by taking into consideration interaction coefficients between the various ions present in solution.
The Ostwald law of dilution provides a satisfactory description of the concentration dependence of the conductivity of weak electrolytes like CH 3 COOH and NH 4 OH. [3] [4] The variation of molar conductivity is essentially due to the incomplete dissociation of weak electrolytes into ions.
An idealized representation of a solution of a 1:1 electrolyte. A description of Debye–Hückel theory includes a very detailed discussion of the assumptions and their limitations as well as the mathematical development and applications. [5] A snapshot of a 2-dimensional section of an idealized electrolyte solution is shown in the picture.
The main electrolytes are confined to water phase. So for example in 10 μL plasma sample, only 9.3 μL is water that contains the electrolyte. Thus if the concentration of an electrolyte, say Na + is determined to be 140 mmol/L, it is the concentration in total plasma volume, not in plasma water volume. [1]
In electrochemistry, cell notation or cell representation is a shorthand method of expressing a reaction in an electrochemical cell.. In cell notation, the two half-cells are described by writing the formula of each individual chemical species involved in the redox reaction across the cell, with all other common ions and inert substances being ignored.
Mott–Schottky plot of a fluorine-doped tin oxide (FTO) semiconductor electrode measured in aqueous electrolyte at different pH, with respect to standard Ag/AgCl electrode. Changing the pH modifies the apparent flatband potential by 570 mV corresponding to a 59 mV displacement per unit of pH.