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The overall chemical reaction is: CO 2 + Ca(OH) 2 → CaCO 3 + H 2 O + heat (in the presence of water) Each mole of CO 2 (44 g) reacts with one mole of calcium hydroxide (74 g) and produces one mole of water (18 g). The reaction can be considered as a strong-base-catalysed, water-facilitated reaction. [5]
Its solubility product K sp of 5.02 × 10 −6 at 25 °C, [1] its dissociation in water is large enough that its solutions are basic according to the following dissolution reaction: Ca(OH) 2 → Ca 2+ + 2 OH −. The solubility is affected by the common-ion effect. Its solubility drastically decreases upon addition of hydroxide or calcium sources.
Its usage varies from about 30 to 50 kilograms (65–110 lb) per ton of steel. The quicklime neutralizes the acidic oxides, SiO 2, Al 2 O 3, and Fe 2 O 3, to produce a basic molten slag. [10] Ground quicklime is used in the production of aerated concrete such as blocks with densities of ca. 0.6–1.0 g/cm 3 (9.8–16.4 g/cu in). [10]
CaH 2: −186.2 Calcium hydroxide: Solid Ca(OH) 2: −986.09 Calcium hydroxide: Aqueous Ca(OH) 2: −1002.82 Calcium oxide: Solid CaO −635.09 Calcium sulfate: Solid CaSO 4: −1434.52 Calcium sulfide: Solid CaS −482.4 Wollastonite: Solid CaSiO 3: −1630 Carbon Solid C 0 Carbon Solid C 1.9 Carbon: Gas C 716.67 Carbon dioxide: Gas CO 2: − ...
The following chart shows the solubility of various ionic compounds in water at 1 atm pressure and room temperature (approx. 25 °C, 298.15 K). "Soluble" means the ionic compound doesn't precipitate, while "slightly soluble" and "insoluble" mean that a solid will precipitate; "slightly soluble" compounds like calcium sulfate may require heat to precipitate.
A solution or suspension of calcium hydroxide is known as limewater and can be used to test for the weak acid carbon dioxide. The reaction Ca(OH) 2 + CO 2 ⇌ Ca 2+ + HCO − 3 + OH − illustrates the basicity of calcium hydroxide. Soda lime, which is a mixture of the strong bases NaOH and KOH with Ca(OH) 2, is used as a CO 2 absorbent.
The standard Gibbs free energy of formation (G f °) of a compound is the change of Gibbs free energy that accompanies the formation of 1 mole of a substance in its standard state from its constituent elements in their standard states (the most stable form of the element at 1 bar of pressure and the specified temperature, usually 298.15 K or 25 °C).
The tetrahydrate crystallizes as a solid solution of Ca 3 (SO 3)2(SO 4). 12H 2 O and Ca 3 (SO 3)2(SO 3). 12H 2 O. The mixed sulfite-sulfate represents an intermediate in the oxidation of the sulfite to the sulfate, as is practiced in the production of gypsum. This solid solution consists of [Ca 3 (SO 3) 2 (H 2 O) 12] 2+ cations and either ...