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In chemistry, the oxidation state, or oxidation number, is the hypothetical charge of an atom if all of its bonds to other atoms were fully ionic. It describes the degree of oxidation (loss of electrons) of an atom in a chemical compound. Conceptually, the oxidation state may be positive, negative or zero.
The formal charge is a tool for estimating the distribution of electric charge within a molecule. [1] [2] The concept of oxidation states constitutes a competing method to assess the distribution of electrons in molecules. If the formal charges and oxidation states of the atoms in carbon dioxide are compared, the following values are arrived at:
If V E is the charge on the atomic core (which is the same as the valence of the atom when all the electrons in the valence shell are bonding), and N E is the corresponding average coordination number, V E /N E is proportional to the electric field at the surface of the core, represented by S E in Eq. 5:
Hypervalent iodine oxyanions are known for oxidation states +1, +3, +5, and +7; organic analogues of these moieties are known for each oxidation state except +7. In terms of chemical behavior, λ 3 ‑ and λ 5 ‑iodanes are generally oxidizing and/or electrophilic species. They have been widely applied towards those ends in organic synthesis. [1]
The oxidation states are also maintained in articles of the elements (of course), and systematically in the table {{Infobox element/symbol-to-oxidation-state}} See also [ edit ]
As anticipated by its hydride clusters, boron forms a variety of stable compounds with formal oxidation state less than three. B 2 F 4 and B 4 Cl 4 are well characterized. [6] Ball-and-stick model of superconductor magnesium diboride. Boron atoms lie in hexagonal aromatic graphite-like layers, with a charge of −1 on each boron atom.
The formal oxidation state of the central nickel atom therefore ranges from +II to +IV in the above transformations (see Figure). However, the formal oxidation state is different from the real (spectroscopic) oxidation state based on the (spectroscopic) metal d-electron configuration. The stilbene-1,2-dithiolate behaves as a redox non-innocent ...
The formal oxidation state of the nitrogen atom in nitrite is +3. This means that it can be either oxidized to oxidation states +4 and +5, or reduced to oxidation states as low as −3. Standard reduction potentials for reactions directly involving nitrous acid are shown in the table below: [4]