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Hammond's postulate (or alternatively the Hammond–Leffler postulate), is a hypothesis in physical organic chemistry which describes the geometric structure of the transition state in an organic chemical reaction. [1] First proposed by George Hammond in 1955, the postulate states that: [2]
Molecular Koch's postulates are a set of experimental criteria that must be satisfied to show that a gene found in a pathogenic microorganism encodes a product that contributes to the disease caused by the pathogen. Genes that satisfy molecular Koch's postulates are often referred to as virulence factors.
Koch's postulates (/ k ɒ x / KOKH) [2] are four criteria designed to establish a causal relationship between a microbe and a disease. The postulates were formulated by Robert Koch and Friedrich Loeffler in 1884, based on earlier concepts described by Jakob Henle , and the statements were refined and published by Koch in 1890. [ 3 ]
In effect, they considered nitrogen dioxide as an AX 2 E 0.5 molecule, with a geometry intermediate between NO + 2 and NO − 2. Similarly, chlorine dioxide (ClO 2) is an AX 2 E 1.5 molecule, with a geometry intermediate between ClO + 2 and ClO − 2. [citation needed] Finally, the methyl radical (CH 3) is predicted to be trigonal pyramidal ...
The first systematic approach for synthetic geometry is Euclid's Elements. However, it appeared at the end of the 19th century that Euclid's postulates were not sufficient for characterizing geometry. The first complete axiom system for geometry was given only at the end of the 19th century by David Hilbert. At the same time, it appeared that ...
The theory is based on two postulates: (1) that the mathematical forms of the laws of physics are invariant in all inertial systems; and (2) that the speed of light in vacuum is constant and independent of the source or observer. Reconciling the two postulates requires a unification of space and time into the frame-dependent concept of spacetime.
In Euclid's Elements, the first 28 Propositions and Proposition 31 avoid using the parallel postulate, and therefore are valid in absolute geometry.One can also prove in absolute geometry the exterior angle theorem (an exterior angle of a triangle is larger than either of the remote angles), as well as the Saccheri–Legendre theorem, which states that the sum of the measures of the angles in ...
Elliptic geometry is an example of a geometry in which Euclid's parallel postulate does not hold. Instead, as in spherical geometry , there are no parallel lines since any two lines must intersect. However, unlike in spherical geometry, two lines are usually assumed to intersect at a single point (rather than two).