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Peter William Atkins FRSC (born 10 August 1940) is an English chemist and a Fellow of Lincoln College at the University of Oxford.He retired in 2007. He is a prolific writer of popular chemistry textbooks, including Physical Chemistry, Inorganic Chemistry, and Molecular Quantum Mechanics.
Non-stoichiometric compounds are chemical compounds, almost always solid inorganic compounds, having elemental composition whose proportions cannot be represented by a ratio of small natural numbers (i.e. an empirical formula); most often, in such materials, some small percentage of atoms are missing or too many atoms are packed into an ...
Some chemistry textbooks [3] as well as the widely used CRC Handbook of Chemistry and Physics [4] define lattice energy with the opposite sign, i.e. as the energy required to convert the crystal into infinitely separated gaseous ions in vacuum, an endothermic process. Following this convention, the lattice energy of NaCl would be +786 kJ/mol.
Inorganic compounds exhibit a range of bonding properties. Some are ionic compounds, consisting of very simple cations and anions joined by ionic bonding.Examples of salts (which are ionic compounds) are magnesium chloride MgCl 2, which consists of magnesium cations Mg 2+ and chloride anions Cl −; or sodium hydroxide NaOH, which consists of sodium cations Na + and hydroxide anions OH −.
Latimer diagrams can be used in the construction of Frost diagrams, as a concise summary of the standard electrode potentials relative to the element.Since Δ r G o = -nFE o, the electrode potential is a representation of the Gibbs energy change for the given reduction.
3 Inorganic chemistry problems. 4 Biochemistry problems. ... Download as PDF; Printable version; ... This article needs attention from an expert in chemistry.
A solubility equilibrium exists when a chemical compound in the solid state is in chemical equilibrium with a solution containing the compound. This type of equilibrium is an example of dynamic equilibrium in that some individual molecules migrate between the solid and solution phases such that the rates of dissolution and precipitation are equal to one another.
When the pH of the solution is increased by adding an alkaline solution to it, the extent of hydrolysis increases. Measurements of pH or colour change are used to derive the equilibrium constant for the reaction. Further hydrolysis may occur, producing dimeric, trimeric or polymeric species containing hydroxy- or oxy- groups.