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Phosphorus pentasulfide is obtained by the reaction of liquid white phosphorus (P 4) with sulfur above 300 °C. The first synthesis of P 4 S 10 by Berzelius in 1843 [ 5 ] was by this method. Alternatively, P 4 S 10 can be formed by reacting elemental sulfur or pyrite , FeS 2 , with ferrophosphorus , a crude form of Fe 2 P (a byproduct of white ...
Water is the medium of the oceans, the medium which carries all the substances and elements involved in the marine biogeochemical cycles. Water as found in nature almost always includes dissolved substances, so water has been described as the "universal solvent" for its ability to dissolve so many substances.
Phosphorus pentoxide crystallizes in at least four forms or polymorphs.The most familiar one, a metastable form [1] (shown in the figure), comprises molecules of P 4 O 10.Weak van der Waals forces hold these molecules together in a hexagonal lattice (However, in spite of the high symmetry of the molecules, the crystal packing is not a close packing [2]).
Energy flow is a unidirectional and noncyclic pathway, whereas the movement of mineral nutrients is cyclic. Mineral cycles include the carbon cycle, sulfur cycle, nitrogen cycle, water cycle, phosphorus cycle, oxygen cycle, among others that continually recycle along with other mineral nutrients into productive ecological nutrition.
The ocean plays a key role in the water cycle as it is the source of 86% of global evaporation. [2] The water cycle involves the exchange of energy, which leads to temperature changes. When water evaporates, it takes up energy from its surroundings and cools the environment. When it condenses, it releases energy and warms the environment.
Recent studies indicate a hydrological cycle of water-ammonia vastly different to the type operating on terrestrial planets like Earth [18] and also a cycle of hydrogen sulfide. [19] Significant chemical cycles exist on Jupiter's moons. Recent evidence points to Europa possessing several active cycles, most notably a water cycle. [20]
The S–I cycle consists of three chemical reactions whose net reactant is water and whose net products are hydrogen and oxygen. All other chemicals are recycled. The S–I process requires an efficient source of heat. More than 352 thermochemical cycles have been described for water splitting by thermolysis. [21]
The Perkow reaction is a competing reaction pathway for α-bromo- and α-chloroketones. Under the reaction conditions a mixture of the Perkow product and the normal Arbuzov product occur, usually favoring the Perkow product by a significant amount. Using higher temperatures during the reaction can lead to favoring of the Arbuzov product.