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Graphene doped with various gaseous species (both acceptors and donors) can be returned to an undoped state by gentle heating in vacuum. [22] [24] Even for dopant concentrations in excess of 10 12 cm −2 carrier mobility exhibits no observable change. [24] Graphene doped with potassium in ultra-high vacuum at low temperature can reduce ...
When the Fermi level of graphene is tuned, its optical absorption can be changed. In 2011, researchers reported the first graphene-based optical modulator. Operating at 1.2 GHz without a temperature controller, this modulator has a broad bandwidth (from 1.3 to 1.6 μm) and small footprint (~ 25 μm 2). [94]
In electrochemistry, the electrochemical potential of electrons (or any other species) is the total potential, including both the (internal, nonelectrical) chemical potential and the electric potential, and is by definition constant across a device in equilibrium, whereas the chemical potential of electrons is equal to the electrochemical ...
However, when formed into a graphene oxide-based capillary membrane, both liquid water and water vapor flow through as quickly as if the membrane were not present. [223] In 2022, researchers evaluated the biological effects of low doses on graphene oxide on larvae and imago of Drosophila melanogaster. Results show that oral administration of ...
Electrochemical biosensors, based on enzymes, work through the enzymatic catalysis of reactions that directly or indirectly produce or consume electrons (such enzymes are rightly called redox enzymes). The sensor design usually consists of three electrodes; a reference electrode, a working electrode, and a counter electrode.
Graphene oxide flakes in polymers display enhanced photo-conducting properties. [10] Graphene is normally hydrophobic and impermeable to all gases and liquids (vacuum-tight). However, when formed into graphene oxide-based capillary membrane, both liquid water and water vapor flow through as quickly as if the membrane was not present. [11]
In principle, ammonia has an extremely small electrochemical window, but thermodynamically-favored reactions less than 1 V outside the window are very slow. Consequently, the electrochemical window for many practical reactions is much larger, comparable to water. [3] Ionic liquids famously have a very large electrochemical window, about 4–5 V ...
In electrochemistry, exchange current density is a parameter used in the Tafel equation, Butler–Volmer equation and other electrochemical kinetics expressions. The Tafel equation describes the dependence of current for an electrolytic process to overpotential.