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  2. Isoelectronicity - Wikipedia

    en.wikipedia.org/wiki/Isoelectronicity

    , Ca 2+, and Sc 3+ and the anions Cl −, S 2−, and P 3− are all isoelectronic with the Ar atom. CO, CN −, N 2, and NO + are isoelectronic because each has two atoms triple bonded together, and due to the charge have analogous electronic configurations (N − is identical in electronic configuration to O so CO is identical electronically ...

  3. Isolobal principle - Wikipedia

    en.wikipedia.org/wiki/Isolobal_principle

    Isolobal compounds are analogues to isoelectronic compounds that share the same number of valence electrons and structure. A graphic representation of isolobal structures, with the isolobal pairs connected through a double-headed arrow with half an orbital below, is found in Figure 1. Figure 1: Basic example of the isolobal analogy

  4. Metal nitrosyl complex - Wikipedia

    en.wikipedia.org/wiki/Metal_nitrosyl_complex

    In this example, the cyanide ligands are "innocent", i.e., they have a charge of −1 each, −5 total. To balance the fragment's overall charge, the charge on {CrNO} is thus +2 (−3 = −5 + 2). Using the neutral electron counting scheme, Cr has 6 d electrons and NO· has one electron for a total of 7. Two electrons are subtracted to take ...

  5. Bond order - Wikipedia

    en.wikipedia.org/wiki/Bond_order

    In chemistry, bond order is a formal measure of the multiplicity of a covalent bond between two atoms. As introduced by Gerhard Herzberg, [1] building off of work by R. S. Mulliken and Friedrich Hund, bond order is defined as the difference between the numbers of electron pairs in bonding and antibonding molecular orbitals.

  6. Einstein–Podolsky–Rosen paradox - Wikipedia

    en.wikipedia.org/wiki/Einstein–Podolsky–Rosen...

    In these "true" states, the positron going to Bob always has spin values opposite to the electron going to Alice, but the values are otherwise completely random. For example, the first pair emitted by the source might be "(+z, −x) to Alice and (−z, +x) to Bob", the next pair "(−z, −x) to Alice and (+z, +x) to Bob", and so forth ...

  7. Polyhedral skeletal electron pair theory - Wikipedia

    en.wikipedia.org/wiki/Polyhedral_skeletal...

    Pb 210. When counting electrons for each cluster, the number of valence electrons is enumerated. For each transition metal present, 10 electrons are subtracted from the total electron count. For example, in Rh 6 (CO) 16 the total number of electrons would be 6 × 9 + 16 × 2 − 6 × 10 = 86 – 60 = 26.

  8. Ion association - Wikipedia

    en.wikipedia.org/wiki/Ion_association

    In chemistry, ion association is a chemical reaction whereby ions of opposite electric charge come together in solution to form a distinct chemical entity. [1] [2] Ion associates are classified, according to the number of ions that associate with each other, as ion pairs, ion triplets, etc. Ion pairs are also classified according to the nature of the interaction as contact, solvent-shared or ...

  9. Mirror nuclei - Wikipedia

    en.wikipedia.org/wiki/Mirror_nuclei

    In physics, mirror nuclei are a pair of isobars of two different elements where the number of protons of isobar one (Z 1) equals the number of neutrons of isobar two (N 2) and the number of protons of isotope two (Z 2) equals the number of neutrons in isotope one (N 1); in short: Z 1 = N 2 and Z 2 = N 1.