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In an aqueous solution, precipitation is the "sedimentation of a solid material (a precipitate) from a liquid solution". [1] [2] The solid formed is called the precipitate. [3] In case of an inorganic chemical reaction leading to precipitation, the chemical reagent causing the solid to form is called the precipitant. [4]
In chemistry, the common-ion effect refers to the decrease in solubility of an ionic precipitate by the addition to the solution of a soluble compound with an ion in common with the precipitate. [1] This behaviour is a consequence of Le Chatelier's principle for the equilibrium reaction of the ionic association / dissociation .
They are present in total ionic equations to balance the charges of the ions. Whereas the Cu 2+ and CO 2− 3 ions combine to form a precipitate of solid CuCO 3. In reaction stoichiometry, spectator ions are removed from a complete ionic equation to form a net ionic equation. For the above example this yields:
Silver phosphate is formed as a yellow solid precipitate by the reaction between a soluble silver salt, such as silver nitrate, with a soluble orthophosphate. [3] Its solubility product is 8.89×10 −17 mol 4 ·dm −2. [4] [5] The precipitation reaction is analytically significant [6] and can be used in qualitative or quantitative analysis. [7]
There are a few acid/base reactions that produce a precipitate in addition to the water molecule shown above. An example is the reaction of barium hydroxide with phosphoric acid, which produces not only water but also the insoluble salt barium phosphate. In this reaction, there are no spectator ions, so the net ionic equation is the same as the ...
Mass transfer is the net movement of mass from one location (usually meaning stream, phase, fraction, or component) to another. Mass transfer occurs in many processes, such as absorption, evaporation, drying, precipitation, membrane filtration, and distillation. Mass transfer is used by different scientific disciplines for different processes ...
Reactions can be exothermic, where ΔH is negative and energy is released. Typical examples of exothermic reactions are combustion, precipitation and crystallization, in which ordered solids are formed from disordered gaseous or liquid phases.
Golden rain demonstration is made by combining two colorless solutions, potassium iodide solution and Lead(II) nitrate solution at room temperature to form yellow precipitate. During the chemical reaction, golden particles gently drop from the top of Erlenmeyer flask to the bottom, similar to watching the rain through a window.