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Fluorine is a chemical element; it has symbol F and atomic number 9. It is the lightest halogen [note 1] and exists at standard conditions as pale yellow diatomic gas. Fluorine is extremely reactive as it reacts with all other elements except for the light inert gases. It is highly toxic.
Fluorine's chemistry is dominated by its strong tendency to gain an electron. It is the most electronegative element and elemental fluorine is a strong oxidant. The removal of an electron from a fluorine atom requires so much energy that no known reagents are known to oxidize fluorine to any positive oxidation state. [20]
The electronegativity of the fluorine strongly polarizes the electron density that exists between the carbon and the fluorine, but not enough to produce ions which would allow it to dissolve in the water. The carbon and fluorine in Teflon (PTFE) both have an electronic charge of zero since they form a covalent bond, but few scientists describe ...
It is to be expected that the electronegativity of an element will vary with its chemical environment, [7] but it is usually considered to be a transferable property, that is to say that similar values will be valid in a variety of situations. Caesium is the least electronegative element (0.79); fluorine is the most (3.98).
Fluorine is highly electronegative, resulting in this significant decrease in bond angle. In predicting the bond angle of water, Bent's rule suggests that hybrid orbitals with more s character should be directed towards the lone pairs, while that leaves orbitals with more p character directed towards the hydrogens, resulting in deviation from ...
Fluorine is the thirteenth most abundant element on Earth and the 24th most abundant element in the universe. It is the most electronegative element and it is highly reactive. Thus, it is rarely found in its elemental state, although elemental fluorine has been identified in certain geochemical contexts. [3]
Fluorine is an insulator in all of its forms. It has a high ionisation energy (1681 kJ/mol), high electron affinity (328 kJ/mol), and high electronegativity (3.98). Fluorine is a powerful oxidising agent (F 2 + 2e → 2HF = 2.87 V at pH 0); "even water, in the form of steam, will catch fire in an atmosphere of fluorine". [9]
However, 2+ ions (Be 2+) or even 1+ (Li +) show some polarizing power because their sizes are so small (e.g., LiI is ionic but has some covalent bonding present). Note that this is not the ionic polarization effect that refers to the displacement of ions in the lattice due to the application of an electric field.