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Polyatomic ions often are useful in the context of acid–base chemistry and in the formation of salts. Often, a polyatomic ion can be considered as the conjugate acid or base of a neutral molecule. For example, the conjugate base of sulfuric acid (H 2 SO 4) is the polyatomic hydrogen sulfate anion (HSO − 4).
The cation is always named first. Ions can be metals, non-metals or polyatomic ions. Therefore, the name of the metal or positive polyatomic ion is followed by the name of the non-metal or negative polyatomic ion. The positive ion retains its element name whereas for a single non-metal anion the ending is changed to -ide.
Each ion can be either monatomic (termed simple ion), such as sodium (Na +) and chloride (Cl −) in sodium chloride, or polyatomic, such as ammonium (NH + 4) and carbonate (CO 2− 3) ions in ammonium carbonate. Salts containing basic ions hydroxide (OH −) or oxide (O 2−) are classified as bases, such as sodium hydroxide and potassium oxide.
(aq) signifies that the ion is aquated, with cations having a chemical formula [M(H 2 O) p] q+ and anions whose state of aquation is generally unknown. For convenience (aq) is not shown in the rest of this article as the number of water molecules that are attached to the ions is irrelevant in regard to hydrolysis. This reaction occurs ...
Types of peroxides, from top to bottom: peroxide ion, organic peroxide, organic hydroperoxide, peracid. The peroxide group is marked in blue. R, R 1 and R 2 mark hydrocarbon moieties. The most common peroxide is hydrogen peroxide (H 2 O 2), colloquially known simply as "peroxide". It is marketed as solutions in water at various concentrations.
Ions consisting of only a single atom are termed atomic or monatomic ions, while two or more atoms form molecular ions or polyatomic ions. In the case of physical ionization in a fluid (gas or liquid), "ion pairs" are created by spontaneous molecule collisions, where each generated pair consists of a free electron and a positive ion. [5]
This is sometimes the case when multiple atoms of the same type surround the central atom, and is especially common for polyatomic ions. When this situation occurs, the molecule's Lewis structure is said to be a resonance structure, and the molecule exists as a resonance hybrid. Each of the different possibilities is superimposed on the others ...
In coordination chemistry, a bridging ligand is a ligand that connects two or more atoms, usually metal ions. [1] The ligand may be atomic or polyatomic. Virtually all complex organic compounds can serve as bridging ligands, so the term is usually restricted to small ligands such as pseudohalides or to ligands that are specifically designed to ...