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The electron can be transferred to another molecule. As the ionized pigment returns to the ground state, it takes up an electron and gives off energy to the oxygen evolving complex so it can split water into electrons, protons, and molecular oxygen (after receiving energy from the pigment four times).
The biochemical capacity to use water as the source for electrons in photosynthesis evolved once, in a common ancestor of extant cyanobacteria (formerly called blue-green algae). The geological record indicates that this transforming event took place early in Earth's history, at least 2450–2320 million years ago (Ma), and, it is speculated ...
One of the electrons of excited P680* will be transferred to a non-fluorescent molecule, which ionizes the chlorophyll and boosts its energy further, enough that it can split water in the oxygen evolving complex (OEC) of PSII and recover its electron. [citation needed] At the heart of the OEC are 4 Mn atoms, each of which can trap one electron ...
By replenishing lost electrons with electrons from the splitting of water, photosystem II provides the electrons for all of photosynthesis to occur. The hydrogen ions (protons) generated by the oxidation of water help to create a proton gradient that is used by ATP synthase to generate ATP.
The free energy created is then used, via a chain of nearby electron acceptors, for a transfer of hydrogen atoms (as protons and electrons) from H 2 O or hydrogen sulfide towards carbon dioxide, eventually producing glucose. These electron transfer steps ultimately result in the conversion of the energy of photons to chemical energy.
In photophosphorylation, light energy is used to pump protons across a biological membrane, mediated by flow of electrons through an electron transport chain. This stores energy in a proton gradient. As the protons flow back through an enzyme called ATP synthase, ATP is generated from ADP and inorganic
The protons in the lumen come from three primary sources. Photolysis by photosystem II oxidises water to oxygen, protons and electrons in the lumen. The transfer of electrons from photosystem II to plastoquinone during non-cyclic electron transport consumes two protons from the stroma. These are released in the lumen when the reduced ...
ET describes the mechanism by which electrons are transferred in redox reactions. [2] Electrochemical processes are ET reactions. ET reactions are relevant to photosynthesis and respiration and commonly involve transition metal complexes. [3] [4] In organic chemistry ET is a step in some industrial polymerization reactions.