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In atomic physics, the effective nuclear charge is the actual amount of positive (nuclear) charge experienced by an electron in a multi-electron atom. The term "effective" is used because the shielding effect of negatively charged electrons prevent higher energy electrons from experiencing the full nuclear charge of the nucleus due to the repelling effect of inner layer.
Slater's rules. In quantum chemistry, Slater's rules provide numerical values for the effective nuclear charge in a many-electron atom. Each electron is said to experience less than the actual nuclear charge, because of shielding or screening by the other electrons. For each electron in an atom, Slater's rules provide a value for the screening ...
In chemistry, a formal charge (F.C. or q*), in the covalent view of chemical bonding, is the hypothetical charge assigned to an atom in a molecule, assuming that electrons in all chemical bonds are shared equally between atoms, regardless of relative electronegativity. [1][2] In simple terms, formal charge is the difference between the number ...
This is the energy per mole necessary to remove electrons from gaseous atoms or atomic ions. The first molar ionization energy applies to the neutral atoms. The second, third, etc., molar ionization energy applies to the further removal of an electron from a singly, doubly, etc., charged ion. For ionization energies measured in the unit eV, see ...
Bjerrum length. The Bjerrum length (after Danish chemist Niels Bjerrum 1879–1958 [1]) is the separation at which the electrostatic interaction between two elementary charges is comparable in magnitude to the thermal energy scale, , where is the Boltzmann constant and is the absolute temperature in kelvins. This length scale arises naturally ...
The atomic core has a positive electric charge called the core charge and is the effective nuclear charge experienced by an outer shell electron. In other words, core charge is an expression of the attractive force experienced by the valence electrons to the core of an atom which takes into account the shielding effect of core electrons.
This page shows the electron configurations of the neutral gaseous atoms in their ground states. For each atom the subshells are given first in concise form, then with all subshells written out, followed by the number of electrons per shell. For phosphorus (element 15) as an example, the concise form is [Ne] 3s 2 3p 3.
The data below tabulates standard electrode potentials (E °), in volts relative to the standard hydrogen electrode (SHE), at: Absolute partial pressure 101.325 kPa (1.00000 atm; 1.01325 bar) for each gaseous reagent — the convention in most literature data but not the current standard state (100 kPa). Variations from these ideal conditions ...