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Sand-based athletic fields are sports turf playing fields constructed on top of sand surfaces. It is important that turf managers select the most suitable type of sand when constructing these fields, as sands with different shapes offer varied pros and cons. Regular maintenance of sand-based athletic fields is just as important as the initial construction of the field. [1]
In organic chemistry, the Mannich reaction is a three-component organic reaction that involves the amino alkylation of an acidic proton next to a carbonyl (C=O) functional group by formaldehyde (H−CHO) and a primary or secondary amine (−NH 2) or ammonia (NH 3). [1] The final product is a β-amino-carbonyl compound also known as a Mannich base.
In 2019, Lan et al. proposed a strategy to apply their chiral amine catalyst with minimal modification to the Mannich reaction of alkynyl ketiminoesters. (scheme 25) [ 20 ] Their application shows that catalyst 26 and MeCN can be replaced by 28 and dichloroethane for many alkynyl trifluoromethyl-, pyrazolinone-derived-, and isatin-derived ...
Mixing can be achieved within seconds at the smaller scales used in flow chemistry. Heat transfer is intensified. Mostly, because the area to volume ratio is large. As a result, endothermic and exothermic reactions can be thermostated easily and consistently. The temperature gradient can be steep, allowing efficient control over reaction time.
A nitrogen bound to both a good electrofuge and a good nucleofuge is known as a nitrenoid (for its resemblance to a nitrene). [2] Nitrenes lack a full octet of electrons are thus highly electrophilic; nitrenoids exhibit analogous behavior and are often good substrates for electrophilic amination reactions.
The amine concentration in the absorbent aqueous solution is an important parameter in the design and operation of an amine gas treating process. Depending on which one of the following four amines the unit was designed to use and what gases it was designed to remove, these are some typical amine concentrations, expressed as weight percent of ...
This guideline applies to amino aldehydes, amino-ketones, and amino-esters; indeed a molecule cannot carry simultaneously (unprotected) aldehyde and amine groups. Aminoacetone , the simplest amino ketone, cannot be isolated as a liquid or solid, [ 3 ] and 2-aminobenzaldehyde oligomerizes in solution or in the melt. [ 4 ]
With the expression above, a membrane system for a binary mixture can be sufficiently defined. it can be seen that the total flow across the membrane is strongly dependent on the relation between the feed and permeate pressures. The ratio of feed pressure (p ') over permeate pressure (p ") is defined as the membrane pressure ratio (θ).