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This is a list of important publications in chemistry, organized by field. [1] [2] [3] [4]Some factors that correlate with publication notability include: Topic creator – A publication that created a new topic.
The modern synthesis was formulated before the elucidation of the double-helix structure of DNA and the establishment of molecular biology in its current status of prominence. Given what was known at the time a simple, powerful model of genetic change through undirected mutation (loosely described as " random ") and natural selection, was seen ...
With microsomes there, cell-free protein synthesis demonstrates cotranslational transport of the protein into the microsome and therefore the removal of the signal sequence. This process produces a mature protein chain. Studies have looked into the cell-free protein synthesis process when microsomes have their bound ribosomes stripped away from ...
Biologists, however, have not limited their application of the term neo-Darwinism to the historical synthesis. For example, Ernst Mayr wrote in 1984 that: The term neo-Darwinism for the synthetic theory [of the early 20th century] is sometimes considered wrong, because the term neo-Darwinism was coined by Romanes in 1895 as a designation of Weismann's theory.
Synthesis-dependent strain annealing is the most preferred repair mechanism in somatic cells. [3] The pathway of SDSA is similar to DSBR until just after the D-loop formation. Instead of forming Holliday junctions after DNA synthesis, the nascent strand dissociates via RETL1 helicase and anneals back to the other end of the resected strand.
Zeolite synthesis involves sol-gel-like processes. The product properties depend on reaction mixture composition, pH of the system, operating temperature, pre-reaction 'seeding' time, reaction time as well as the templates used. In the sol-gel process, other elements (metals, metal oxides) can be easily incorporated.
Allylic shifts become the dominant reaction pathway when there is substantial resistance to a normal (non-allylic) substitution. For nucleophilic substitution, such resistance is known when there is substantial steric hindrance at or around the leaving group, or if there is a geminal substituent destabilizing an accumulation of positive charge.
The Debus–Radziszewski imidazole synthesis is a multi-component reaction used for the synthesis of imidazoles from a 1,2-dicarbonyl, an aldehyde, and ammonia or a primary amine. The method is used commercially to produce several imidazoles. [1] The process is an example of a multicomponent reaction.