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2 nh 4 clo 3 + baco 3 → ba(clo 3) 2 + 2 nh 3 + h 2 o + co 2 The reaction initially produces barium chlorate and ammonium carbonate ; boiling the solution decomposes the ammonium carbonate and drives off the resulting ammonia and carbon dioxide, leaving only barium chlorate in solution.
Barium hypochlorite is a chemical compound with the chemical formula Ba(O Cl) 2 (also written as Ba(ClO) 2). It is the barium salt of hypochlorous acid. It consists of barium cations Ba 2+ and hypochlorite anions − OCl.
The need for dehydrating compounds has increased with the use of chemical reactions employing gases under pressure, as the water must be removed from the air prior to the reaction taking place. [ 8 ] Barium perchlorate is also used for the determination of small concentrations (down to 10 ppm, with an accuracy of +/- 1 ppm) of sulfate. [ 5 ]
The coordination number of Ba 2+ increases from 9 to 10. [13] In aqueous solution BaCl 2 behaves as a simple salt; in water it is a 1:2 electrolyte [clarification needed] and the solution exhibits a neutral pH. Its solutions react with sulfate ion to produce a thick white solid precipitate of barium sulfate. BaCl 2 + Na 2 SO 4 → 2 NaCl + BaSO 4
The following chart shows the solubility of various ionic compounds in water at 1 atm pressure and room temperature (approx. 25 °C, 298.15 K). "Soluble" means the ionic compound doesn't precipitate, while "slightly soluble" and "insoluble" mean that a solid will precipitate; "slightly soluble" compounds like calcium sulfate may require heat to precipitate.
The term can also refer to chemical compounds containing this anion, with chlorates being the salts of chloric acid. Other oxyanions of chlorine can be named "chlorate" followed by a Roman numeral in parentheses denoting the oxidation state of chlorine: e.g., the ClO − 4 ion commonly called perchlorate can also be called chlorate(VII).
Chlorine perchlorate is a chemical compound with the formula Cl 2 O 4. This chlorine oxide is an asymmetric oxide, with one chlorine atom in +1 oxidation state and the other +7, with proper formula ClOClO 3. It is produced by the photodimerization of chlorine dioxide (ClO 2) at room temperature by 436 nm ultraviolet light: [2] [3] [4] 2ClO 2 ...
It may be produced from barium chlorate through its reaction with sulfuric acid, which results in a solution of chloric acid and insoluble barium sulfate precipitate: [2] Ba(ClO 3) 2 + H 2 SO 4 → 2 HClO 3 + BaSO 4. The chlorate must be dissolved in boiling water and the acid should be somewhat diluted in water and heated before mixing.