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Ceric ammonium nitrate (CAN) is the inorganic compound with the formula (NH 4) 2 [Ce(NO 3) 6]. This orange-red, water-soluble cerium salt is a specialised oxidizing agent in organic synthesis and a standard oxidant in quantitative analysis .
Ammonium nitrate is an important fertilizer with NPK rating 34-0-0 (34% nitrogen). [17] It is less concentrated than urea (46-0-0), giving ammonium nitrate a slight transportation disadvantage. Ammonium nitrate's advantage over urea is that it is more stable and does not rapidly lose nitrogen to the atmosphere.
The term "calcium ammonium nitrate" is applied to multiple different, but closely related formulations. One variety of calcium ammonium nitrate is made by adding powdered limestone to ammonium nitrate; [1] [2] another, fully water-soluble version, is a mixture of calcium nitrate and ammonium nitrate, which crystallizes as a hydrated double salt: [3] 5Ca(NO 3) 2 •NH 4 NO 3 •10H 2 O.
Cerium(III) sulfate is one of the few salts whose solubility in water decreases with rising temperature. [12] Ceric ammonium nitrate. Due to ligand-to-metal charge transfer, aqueous cerium(IV) ions are orange-yellow. [13] Aqueous cerium(IV) is metastable in water [14] and is a strong oxidizing agent that oxidizes hydrochloric acid to give ...
Basic cerium(IV) nitrate has the formula Ce(NO 3) 3.OH.3H 2 O. It also forms upon evaporation of solutions of cerium(IV) in nitric acid. [10] When this meets ammonia in water solution it reacts to form ceric ammonium nitrate and ceric hydroxide. [10] Basic dicerium nitrate has the formula Ce 2 O(NO 3) 6 (H 2 O) 6 ·2H 2 O. Again it crystallizes ...
The compound ceric ammonium nitrate (CAN) (NH 4) 2 [Ce(NO 3) 6] is the most common cerium compound encountered in the laboratory. The six nitrate ligands bind as bidentate ligands . The complex [Ce(NO 3 ) 6 ] 2− is 12-coordinate, a high coordination number which emphasizes the large size of the Ce 4+ ion.