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The preparation of salt solutions often takes place in unsealed beakers. In this case the conductivity of purified water often is 10 to 20 times higher. A discussion can be found below. Typical drinking water is in the range of 200–800 μS/cm, while sea water is about 50 mS/cm [3] (or 0.05 S/cm).
Electrical conductivity of water samples is used as an indicator of how salt-free, ion-free, or impurity-free the sample is; the purer the water, the lower the conductivity (the higher the resistivity). Conductivity measurements in water are often reported as specific conductance, relative to the conductivity of pure water at 25 °C.
A river or lake water with a salinity of around 70 mg/L will typically have a specific conductivity at 25 °C of between 80 and 130 μS/cm. The actual ratio depends on the ions present. [14] The actual conductivity usually changes by about 2% per degree Celsius, so the measured conductivity at 5 °C might only be in the range of 50–80 μS/cm.
m is the molar conductivity at infinite dilution (or limiting molar conductivity), which can be determined by extrapolation of Λ m as a function of √ c, K is the Kohlrausch coefficient, which depends mainly on the stoichiometry of the specific salt in solution, α is the dissociation degree even for strong concentrated electrolytes,
The Bresle method uses the difference of conductivity of salts in water, each salt having a characteristic conductivity-versus-concentration relationship. The correlation between concentration and conductivity can be found in "Handbook of Chemistry and Physics". This relationship is useful only if the dissolved salt is known.
This conductivity gain upon dissolving or melting is sometimes used as a defining characteristic of salts. [76] In some unusual salts: fast-ion conductors, and ionic glasses, [53] one or more of the ionic components has a significant mobility, allowing conductivity even while the material as a whole remains solid. [77]
The effect is commonly seen as an effect on the solubility of salts and other weak electrolytes. Adding an additional amount of one of the ions of the salt generally leads to increased precipitation of the salt, which reduces the concentration of both ions of the salt until the solubility equilibrium is reached. The effect is based on the fact ...
Ionic compounds, when dissolved in water, dissociate into ions. The total electrolyte concentration in solution will affect important properties such as the dissociation constant or the solubility of different salts. One of the main characteristics of a solution with dissolved ions is the ionic strength.