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On the molecular level, the interlocked molecules cannot be separated without the breaking of the covalent bonds that comprise the conjoined molecules; this is referred to as a mechanical bond. Examples of mechanically interlocked molecular architectures include catenanes, rotaxanes, molecular knots, and molecular Borromean rings.
The interlocked rings rotate with respect to one another. This motion can often be evaluated by NMR spectroscopy, among other methods.When molecular recognition motifs exist in the finished catenane (usually those that were used to synthesize the catenane), the catenane can have one or more thermodynamically preferred positions of the rings with respect to each other (recognition sites).
Rotaxane synthesis can be carried out via a "capping," "clipping, "slipping" or "active template" mechanism. Synthesis via the capping method relies strongly upon a thermodynamically driven template effect; that is, the "thread" is held within the "macrocycle" by non-covalent interactions, for example rotaxinations with cyclodextrin macrocycles involve exploitation of the hydrophobic effect.
Main-chain polycatenanes are linear catenanes in which the rings are interlocked in a large number of units. They can also be a series of oligomers linked physically even if not interlocked together. The stability of the structure is not only given by mechanical bonds but also hydrogen bonds and π-π interactions between the rings. [2]
In chemistry, molecular Borromean rings are an example of a mechanically-interlocked molecular architecture in which three macrocycles are interlocked in such a way that breaking any macrocycle allows the others to dissociate. They are the smallest examples of Borromean rings.
A molecular topology is an area in chemistry that involves different mechanically-interlocked molecular architectures. Pages in category "Molecular topology" The following 14 pages are in this category, out of 14 total.
In chemistry, molecular Borromean rings are the molecular counterparts of Borromean rings, which are mechanically-interlocked molecular architectures. In 1997, biologist Chengde Mao and coworkers of New York University succeeded in constructing a set of rings from DNA. [44]
Applying chemical topology and knot theory to molecular knots allows biologists to better understand the structures and synthesis of knotted organic molecules. [1] The term knotane was coined by Vögtle et al. in 2000 to describe molecular knots by analogy with rotaxanes and catenanes, which are other mechanically interlocked molecular ...