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A number of materials contract on heating within certain temperature ranges; this is usually called negative thermal expansion, rather than "thermal contraction".For example, the coefficient of thermal expansion of water drops to zero as it is cooled to 3.983 °C (39.169 °F) and then becomes negative below this temperature; this means that water has a maximum density at this temperature, and ...
For a single component system, the "standard" three parameters are the isothermal compressibility , the specific heat at constant pressure , and the coefficient of thermal expansion . For example, the following equations are true:
To distinguish these two thermal expansion equations of state, the latter one is called pressure-dependent thermal expansion equation of state. To deveop the pressure-dependent thermal expansion equation of state, in an compression process at room temperature from (V 0, T 0, P 0) to (V 1, T 0,P 1), a general form of volume is expressed as
Temperature gradients, thermal expansion or contraction and thermal shocks are things that can lead to thermal stress. This type of stress is highly dependent on the thermal expansion coefficient which varies from material to material. In general, the greater the temperature change, the higher the level of stress that can occur.
In thermodynamics, the Joule–Thomson effect (also known as the Joule–Kelvin effect or Kelvin–Joule effect) describes the temperature change of a real gas or liquid (as differentiated from an ideal gas) when it is expanding; typically caused by the pressure loss from flow through a valve or porous plug while keeping it insulated so that no heat is exchanged with the environment.
The temperature of a system in thermal equilibrium is the same as the temperature of any part of it, so temperature is an intensive quantity. If the system is divided by a wall that is permeable to heat or to matter, the temperature of each subsystem is identical. Additionally, the boiling temperature of a substance is an intensive property.
[1] [2] [3] A more fundamental statement was later labelled as the zeroth law after the first three laws had been established. The zeroth law of thermodynamics defines thermal equilibrium and forms a basis for the definition of temperature: if two systems are each in thermal equilibrium with a third system, then they are in thermal equilibrium ...
As quoted in an online version of: David R. Lide (ed), CRC Handbook of Chemistry and Physics, 84th Edition.CRC Press. Boca Raton, Florida, 2003; Section 4, Properties of the Elements and Inorganic Compounds; Physical Properties of the Rare Earth Metals